Science of Dental Materials Flashcards
Why is it important for dental practitioners to have an understanding of dental materials?
The dentist spends much of his professional career handling materials and the success or failure of many forms of treatment depends on the correct selection of materials with adequate properties combined with careful manipulation
What kind of materials are commonly used by dental practitioners as treatment biomaterials?
Metals and Alloys (amalgam)
Polymers (mouthguards and dentures)
Ceramics (crowns and bridges)
Composites (Tooth coloured restorations)
How is the correct material selected for when treating a patient?
Problem is analysed
Requirements are considered along with the availability of the materials.
Requirements and properties are compared and selected before undergoing review.
What materials have an amorphous structure and which have crystalline structures?
Amorphous structures include dental waxes and ceramic crowns.
Crystalline structures include
What is isomerism?
Arrangement of atoms or molecules of many elements or compounds can be changed by altering the surrounding physical conditions. Allotropy and polymorphism are types of isomerism.
What properties are used to characterize dental materials?
Mechanical properties (properties not concerned with the application of force)
Rheological properties (flow properties)
Thermal properties
Chemical properties
Surface phenomena and adhesion
Biological properties
Miscellaneous physical properties
What are the temperature related properties that can be used to characterize mateirals?
Heat of fusion (Heat required to convert 1g of a material from the solid to the liquid state at the melting temperature)
Thermal conductivity (Coefficient of thermal conductivity is the quantity of heat in calories or joules per second passing through a body of 1cm thickness and 1cm2 cross-sectional area when temperature difference is 1 degrees Celsius)
Thermal diffusivity (Measure of transient heat-flow and is defined as thermal conductivity divided by specific heat x density)
Thermal expansion (Change in length per unit length of a material for a 1 degree change in temperature)
What is the heat of fusion and how is it measured?
Heat of fusion (L) is the heat
in calories or joules required to convert 1 gm of a material from the solid to the liquid state at the melting temperature.
Heat of fusion =(L) = q/m
q= total heat
absorped
m=mass of substance melted
What is thermal conductivity and how is it measured? What is its significance?
Coefficient of thermal conductivity (K) is the quantity of heat in calories or joules per second passing through a body of 1 cm thickness and 1 cm2 cross –sectional area, when the
temperature difference is 1°C.
Cal/sec/cm²/(c°/cm) .
Significance: Denture base and metallic fillings
What is specific heat? Why is it important?
The amount of heat needed to raise the temperature of 1 gram of material by 1°C
Melting and casting alloys
What is thermal diffusivity and how is it measured?
The measure of transient heat flow and is defined as the thermal conductivity / Specific heat x Density
What is thermal expansion and how is it measured?
Thermal expansion
It is the change in length per unit length of a material for a 1°C change in temperature and it is calculated as follows:
(Lfinal - Loriginal) / Loriginal x (°C final - °C original)
Volumetric expansion = Linear x 3 (for isotropic
solids)
How can thermal expansion information be applied?
Wax patterns - Increasing coefficient of expansion affects accuracy or rest.
Decreasing in volume on cooling of an alloy needs to be compensated.
Investment, polymorphism of silica
Marginal percolation/leakage
What are the optical properties that are important to consider in dentistry?
Colour
Translucency
Surface texture
Metamerism (change in colour of an object due to change in light source)
What are the electrical properties that are relevant to dental materials?
Galvanism (generated electrical current a patient can feel resulting from dissimilar metals present in a solution that contains ions (oral cavity)) This can also lead to corrosion and pitting (due to metal dissolving)
What is solubility and sorption and how do they affect dental materials?
Both are important criteria for dental materials selection. Lab studies are used to evaluate and rank materials.
Sorption includes absorption and adsorption. Absorption is the uptake of liquid by solid and adsorption is the concentration of molecules at the surface of solid or liquid (eg adsorption of saliva on tooth surface)
What is wettability?
Measure of the affinity of a liquid for a solid indicated by spreading of a drop (eg wetting of denture base by saliva. Wetting of enamel surface by pits and fissures)
How is wettability observed?
Based on the shape of the liquid on the solid surface as identified by contact angle.
Low contact angle = high wettability (hydrophilic if liquid is water)
High contact angle = low wettability (hydrophobic if liquid is water)
What are the most important biological properties of dental materials?
Primary requirements of any dental materials include:
It must be non-toxic, non-irritant, no carcinogenic or allergenic potential, and if used as a filling it should be harmless to the pulp
What happens to biting force from posterior to anterior teeth? What effect does artifical dentition have on the biting forces?
Biting force decreases.
1st and second molars = 580N
Premolars = 310N
Canines = 220N
Incisors = 180N
Artificial replacement of dentition decreases biting force.
What has stronger tensile strength dentin or enamel?
Dentin
What has higher compressive strength dentine or enamel?
Enamel
How is deformation observed in dental materials?
Deformation results in a change in length in any dimension of the material. The change in length is a measure of deformation.
What are the types of deformation?
Elastic deformation (reversible)
Plastic deformation (irreversible or permanent)
What is stress?
Internal reaction to the external applied force per unit area. It is equal to intensity and opposite in direction to the external applied force per unit area.
What is strain?
Defined as a change in length per unit length.
What are the types of stress that can affect materials?
Tensile stress (Results when the body is subjected to 2 sets of forces directed away from each other in the same straight line)
Compressive stress (results when the body is subjected to two sets of forces directed towards each other in the same straight line [normal or axial)
Shear stress (results when the body is subjected to two parallel sets of forces directed towards each other not in the same straight line)
What does the stress-strain curve tell us?
2 portions of the stress-strain curve:
Elastic portion (obeys hook’s law, the strain is directly proportional to the applied stress)
Plastic portion (does not obey hook’s law, strain is not linearly proportional to the applied stress, when stress is removed the original size and shape is not recovered)
How is the engineering stress-strain curve different to the normal stress-strain curve?
The engineering stress - strain curve is that curve where the applied forces are
always divided by the original cross sectional area to calculate the corresponding stress.
What data can we obtain from a stress-strain curve?
Stress related terms:
Proportional limit
Elastic limit
Yield stress
Ultimate stress
Fracture stress