PPT LQ2 PT2 Flashcards
Polymers is made up of repeating units called
Monomers
Characterized by their relatively large molecular masses (10,000 to 100,000 atoms per molecule)
Polymers
Ancient greek polus =
Meros=
Many much & parts
Two types of polymers
Natural and synthetic
Extracted from living organisms such as plants and animals
Natural polymers
Protein (amino acids) nucleic acids (nucleotides) carbohydrates (glucose)
Natural polymers
Synthesize in lab
Synthetic polymers
Nylon in clothing, silicone in kitchenware, and polyethylene terephthalate (pet) in beverage bottles
Synthetic polymers
Classification of polymers
Thermoplastic, elastomer, thermoset
Comparatively weak intermolecular interaction
Thermoplastic
Soften when heated and then return to its initial state when cooled
Thermoplastic
Linear or somewhat branched
Thermoplastic
Credit cards, car bumpers, insulation, and food packaging
Thermoplastic
“Sets” or solidifies permanently; heating cannot change its shape
Thermosetting
Construction and cars, glues, boat hulls, toys, and varnishes
Thermosetting
Easily stretched to several times their unstretched length and quickly revert to their initial state upon removal of applied tension
Elastomers
Cross linked
Elastomers
Rubber bands and other elastics
Elastomers
VULCANIZATION
WAS DISCOVERED
BY CHARLES
GOODYEAR
1839
PARKESINE, THE
FIRST SEMI-
SYNTHETIC
POLYMER, WAS
CREATED BY
ALEXANDER
PARKES
1862
BAKELITE, THE
FIRST COMPLETELY
SYNTHETIC
POLYMER, WAS
CREATED BY LEO
BAEKELAN
1907
MACROMOLECULAR
THEORY WAS
PROPOSED BY
HERMAN
STAUDINGER
1920
POLYETHYLENE
WAS CREATED BY
ICI (IMPERIAL
CHEMICAL
INDUSTRIES); LED
TO HDPE AND LDPE
1933
NYLON WAS
SYNTHESIZED BY
WALLACE
CAROTHERS
1935