Ochem day 6

Question 0

electron withdrawing groups decreases basicity…

Answer 0

amines

Question 1

Amines

Answer 1

electron donating groups increase basisty/nucleophilicity

Question 2

amide formation

Answer 2

2 eq RNH2

Question 3

Amide formation w nitrous acid

Answer 3

HCL, NaNO2 Odegrees

Question 4

Alkylatioin

Answer 4

SN2 CH3Br…. adds Ch3’s too the NH3 group

Question 5

Hofmann elimination

Answer 5

XS CH3I, Ag2O and H2O…. adds CH3 to N that has ethyl on each side

Question 6

monosaccharides

Answer 6

glucose, fructose, galactose

Question 7

oligosaccharides

Answer 7

sucrose (glucose and fructose) and lactose (glucose and galactose) are disacharides

Question 8

polysaccharides

Answer 8

starch, glycogen, cellulose, chitin

Question 9

Dvs L sugars

Answer 9

D- OH on Right…. L OH on Left…..

Question 10

aldose vs ketose

Answer 10

aldose double bond on end…. ketose double bond in middle..

Question 11

pentose vs hexose

Answer 11

5 vs 6 member ring

Question 12

furanose vs pyranose

Answer 12

furanose, is 5 with O… Pyranose is 6 with O

Question 13

acetal vs hemi acetals

Answer 13

Acety.. has OR and OR group… Hemi has OR and OH group

Question 14

anomeric carbon

Answer 14

a sterocenter can point up or down…alpha down… beta up

Question 15

epimers

Answer 15

differ in only one sterogenic center… everything else is the same… very similar

Question 16

reduing sugars….

Answer 16

CuSO4, base… adding an OH to the top…

Question 17

amino acid sequence

Answer 17

primary structure

Question 18

held together by H bonds in the backbone… alpha and beta

Answer 18

secondary structure

Question 19

organization of secondary structure… in globular proteins, hydrophobic residues are sequestered in the interior of the protein while hydrophobic residues are on the outer surface…. disulfide bonds btw cysteine residues

Answer 19

tertiary structure

Question 20

quarternary structure

Answer 20

interattions of multiple subunits (seperate peptide chains) as in hemoglobin

Question 21

Cholestrol

Answer 21

membrane fluididty, steroid precurser

Question 22

Terpenes

Answer 22

isoprene, menthol, viatmin A,

Question 23

Purines

Answer 23

adenine and guanosine

Question 24

pytimidies

Answer 24

cytidine, thymidine, and uracil

Question 25

ATP

Answer 25

3 phosphates, base, and adenine. + water

Question 26

ADP

Answer 26

2 phosphates, base and adenine,