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Y1S1 > MTIOCH - Finals 2 > Flashcards

MTIOCH - Finals 2 Flashcards

1
Q

Compound that resembles benzene

A

Aromatic C.

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2
Q

All aromatic c. confirm to this rule

A

Huckel Rule for Aromaticity

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3
Q

Molecular formula of benzene ring

A

C6H6

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4
Q

Iupac name of benzene

A

1, 3, 5 cyclohexatriene

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5
Q

Benzene
Melts at?
Boils at?
Density?

A

M - 55c
B - 80.1c
D - 0.88

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6
Q

Extracted from benzene

A

Nitrobenzene

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7
Q

Benzene used in drug manufacture

A

Napthalene

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8
Q

Benzene in drug manufacturing (2)

A

Aniline and phenol

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9
Q

Benzene makes a satisfactory fuel when mixed with?

A

Petrol

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10
Q

Who discovered Benzene and when?

A

1825 - Michael Faraday

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11
Q

Benzene is from?

A

Coal tar

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12
Q

Ways of extracting benzene (2)

A

Hydroforming and cyclization

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13
Q

When and who formulated the ring structure?

A

August Kekule in 1865

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14
Q

When coal is heated to _____c in the absence of air, it produces _______

A

450-1200c - Coke

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15
Q

Which are driven pff when coal is heated?

A

Coal tar

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16
Q

Give three industrial solvent under AHC

A

Benzene
Toluene
Xylene

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17
Q

AHC that is insect repellent

A

Napthalene

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18
Q

AHC connected to Anthrax

A

Anthracene

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19
Q

1/3 of our benzene supply comes from here

A

Peteoleum

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20
Q

AHC polar/nonpolar?
density ___ of water?

A

Nonpolar
Less than water

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21
Q

flame that AHC burn _______ its because of?

A

Yellow - incomplete carbon combustion

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22
Q

Cancer forming

A

Carcinogenic

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23
Q

Most have ______ the reason for the name “aroma”

A

Sweet aroma

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24
Q

AHC Halogenation Catalysts (2)

A

Iron (iii) chloride
Iron (iii) bromide

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25
AHC halogenation forms?
Aryl Halide
26
AHC Nitration forms ____ at ____ c
Nitrobenzene at 50c
27
AHC Friedel-Crafts catalyst
Aluminum Chloride Catalyst
28
AHC Friedel-Crafts Alkylation forms? (2)
Alkyl benzene and hydrogen halide
29
Reagents used in side chain oxidation (2)
Potassium Permanganate Potassium dichromate
30
End product of Side-Chain Oxidation
Benzoic Acid
31
What are the 3 Substitution Reaction
Halogenation Nitration Friedel-Crafts Alkylation
32
Which “SCO” uses Potassium Permanganate and Potassium Dichlorite
Side-Chain Oxidation
33
Give 4 alkyl
Methyl Ethyl Isopropyl Sepbutyl
34
Methyl benzene (Common name and attachment)
Toluene CH3
35
Hydroxybenzene (Common name and attachment)
Phenol OH
36
Aminobenzene (Common name and attachment)
Aniline NH2
37
Cyanobenzene (Common name and attachment)
Benzonitrile CN
38
Isopropylbenzene (Common name and attachment)
Cumene CH3 - CH3 | CH3
39
Carboxybenzene (Common name and attachment)
Benzoic Acid C - OH | O
40
Methoxybenzene (Common name and attachment)
Anisole O - CH3
41
Vinylbenzene (Common name and attachment)
Styrene CH = CH2
42
Acetophenone
None C - CH3 || O
43
Types of Disubstituted AC (2)
Xylene Cresol
44
Xylene positioning: 1,2 (Draw it)
Orthopositioning
45
Xylene positioning: 1,3 (Draw it)
Metapositioning
46
Xylene positioning: 1,4 (Draw it)
Parapositioning
47
SN of Xylene
(Number) Dimethylbenzene
48
Parent Name (SN2) of Xylene
(Number) Xylene
49
CN of Xylene
(Letter) Xylene
50
SN1 of Cresol
(Number a) Hydroxy - (number b) methyl benzene
51
SN2 of Cresol
(Number) Cresol
52
CN of Cresol
(Letter) cresol
53
(3) fused ring AHC
- Napthalene - Anthracene - Phenanthrene
54
Character of 3 Fused Ring AHC
Naphtalene - 2 Anthracene - 3 Phenanthrene - 3 na tabingi
55
One or more H of alipathic has been replaced with halogen atoms
Alkyl Halide
56
One or more H of benzene ring has been replaced with halogen atoms
Aryl Halide
57
Most alkyl halide are liquid except with ____ atoms which are gases
Fluorine
58
Organic halides are flammable?
No
59
OHalide that is colorless and nonirritating odor
Carbon Tetrachloride (CCl4)
60
CCL4 is used to make?
Chlorofluoromethanes
61
The rape liquid
Chloroform (CHCl3)
62
Chloroform aka
Trichloromethane
63
Iodoform aka?
Triiodomethane
64
Halide used in Antiseptic and ointment for minor skin disease
Iodoform or Triiodomethane
65
Halide used in aerosol cans
Chlorofluorocarbons or freons
66
CFC means?
Chlorofluorocarbon
67
Halide for non-stick cooking utensils
Polytetrafluoroethene or Teflon
68
Halide used as tropical anesthetic
Ethyl Chloride or Chloroethane
69
Give 3 inhalational general anesthetic
Haloethane Isoflurane Pesflurane
70
Derivative of hydrocarbon with one or more atoms replaced by a hydroxyl
Alcohol
71
General formula of alcohol
R-OH
72
Recite (3) the Classification if Alcohol based in location if OH Group
Primary - 1 Secondary - 2 Tertiary - 3 OH group attached to has (n) carbons attached to it
73
Recite (2) based on the number of OH groups present
Monohydroxy - OH Polyhydroxy - OH - OH | C
74
Recite (2) based on type of parent hydrocarbon attached to
Alipathic - open ended Alicyclic - polygon
75
Recite (2) based on the presence or absence of side chain other than OH group
Straight chain - snake Branched chain - has branches
76
A primary alcohol will yield an _____ molecule when oxidized
Aldehyde
77
A secondary alcohol will yield ______ molecule when oxidized
Ketone
78
A tertiary alcohol will yield ____ when oxidized
No reaction
79
Alkene formation aka?
Intramolecular Dehydration
80
Ether formation aka?
Intermolecular dehydration
81
Alcohol react with ____ to form ester in esterification
Carboxylic acid
82
Methyl Alcohol other names (2)
Methanol Wood Alcohol
83
Ethyl Alcohol other names (2)
Ethanol Grain Alcohol
84
Component of rubbing alcohol
Ethyl alcohol
85
Alcohol ingridient of antifreeze for motor vehicle engines
Ethylene glycol
86
Alcohol unfit for beverages
Denatured alcohol
87
Isopropyl aka?
Isopranol
88
Glycerol, a component if fats aka?
Glycerin
89
Menthol aka?
5-methyl 2-isopropylcyclohexanol
90
Alcohol found in animal fats, oil
Cholesterol
91
Alcohol: vitamin a
Retinol
92
Alcohol: vitamin e
Tocopherol

Y1S1 (31 decks)

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