MTIOCH - Finals 2 Flashcards
Compound that resembles benzene
Aromatic C.
All aromatic c. confirm to this rule
Huckel Rule for Aromaticity
Molecular formula of benzene ring
C6H6
Iupac name of benzene
1, 3, 5 cyclohexatriene
Benzene
Melts at?
Boils at?
Density?
M - 55c
B - 80.1c
D - 0.88
Extracted from benzene
Nitrobenzene
Benzene used in drug manufacture
Napthalene
Benzene in drug manufacturing (2)
Aniline and phenol
Benzene makes a satisfactory fuel when mixed with?
Petrol
Who discovered Benzene and when?
1825 - Michael Faraday
Benzene is from?
Coal tar
Ways of extracting benzene (2)
Hydroforming and cyclization
When and who formulated the ring structure?
August Kekule in 1865
When coal is heated to _____c in the absence of air, it produces _______
450-1200c - Coke
Which are driven pff when coal is heated?
Coal tar
Give three industrial solvent under AHC
Benzene
Toluene
Xylene
AHC that is insect repellent
Napthalene
AHC connected to Anthrax
Anthracene
1/3 of our benzene supply comes from here
Peteoleum
AHC polar/nonpolar?
density ___ of water?
Nonpolar
Less than water
flame that AHC burn _______ its because of?
Yellow - incomplete carbon combustion
Cancer forming
Carcinogenic
Most have ______ the reason for the name “aroma”
Sweet aroma
AHC Halogenation Catalysts (2)
Iron (iii) chloride
Iron (iii) bromide
AHC halogenation forms?
Aryl Halide
AHC Nitration forms ____ at ____ c
Nitrobenzene at 50c
AHC Friedel-Crafts catalyst
Aluminum Chloride Catalyst
AHC Friedel-Crafts Alkylation forms? (2)
Alkyl benzene and hydrogen halide
Reagents used in side chain oxidation (2)
Potassium Permanganate
Potassium dichromate
End product of Side-Chain Oxidation
Benzoic Acid
What are the 3 Substitution Reaction
Halogenation
Nitration
Friedel-Crafts Alkylation
Which “SCO” uses Potassium Permanganate and Potassium Dichlorite
Side-Chain Oxidation
Give 4 alkyl
Methyl
Ethyl
Isopropyl
Sepbutyl
Methyl benzene (Common name and attachment)
Toluene
CH3
Hydroxybenzene (Common name and attachment)
Phenol
OH
Aminobenzene (Common name and attachment)
Aniline
NH2
Cyanobenzene (Common name and attachment)
Benzonitrile
CN
Isopropylbenzene (Common name and attachment)
Cumene
CH3 - CH3
|
CH3
Carboxybenzene (Common name and attachment)
Benzoic Acid
C - OH
|
O
Methoxybenzene (Common name and attachment)
Anisole
O - CH3
Vinylbenzene (Common name and attachment)
Styrene
CH = CH2
Acetophenone
None
C - CH3
||
O
Types of Disubstituted AC (2)
Xylene
Cresol
Xylene positioning: 1,2
(Draw it)
Orthopositioning
Xylene positioning: 1,3
(Draw it)
Metapositioning
Xylene positioning: 1,4
(Draw it)
Parapositioning
SN of Xylene
(Number) Dimethylbenzene
Parent Name (SN2) of Xylene
(Number) Xylene
CN of Xylene
(Letter) Xylene
SN1 of Cresol
(Number a) Hydroxy - (number b) methyl benzene
SN2 of Cresol
(Number) Cresol
CN of Cresol
(Letter) cresol
(3) fused ring AHC
- Napthalene
- Anthracene
- Phenanthrene
Character of 3 Fused Ring AHC
Naphtalene - 2
Anthracene - 3
Phenanthrene - 3 na tabingi
One or more H of alipathic has been replaced with halogen atoms
Alkyl Halide
One or more H of benzene ring has been replaced with halogen atoms
Aryl Halide
Most alkyl halide are liquid except with ____ atoms which are gases
Fluorine
Organic halides are flammable?
No
OHalide that is colorless and nonirritating odor
Carbon Tetrachloride (CCl4)
CCL4 is used to make?
Chlorofluoromethanes
The rape liquid
Chloroform (CHCl3)
Chloroform aka
Trichloromethane
Iodoform aka?
Triiodomethane
Halide used in Antiseptic and ointment for minor skin disease
Iodoform or Triiodomethane
Halide used in aerosol cans
Chlorofluorocarbons or freons
CFC means?
Chlorofluorocarbon
Halide for non-stick cooking utensils
Polytetrafluoroethene or Teflon
Halide used as tropical anesthetic
Ethyl Chloride or Chloroethane
Give 3 inhalational general anesthetic
Haloethane
Isoflurane
Pesflurane
Derivative of hydrocarbon with one or more atoms replaced by a hydroxyl
Alcohol
General formula of alcohol
R-OH
Recite (3) the Classification if Alcohol based in location if OH Group
Primary - 1
Secondary - 2
Tertiary - 3
OH group attached to has (n) carbons attached to it
Recite (2) based on the number of OH groups present
Monohydroxy - OH
Polyhydroxy - OH - OH
|
C
Recite (2) based on type of parent hydrocarbon attached to
Alipathic - open ended
Alicyclic - polygon
Recite (2) based on the presence or absence of side chain other than OH group
Straight chain - snake
Branched chain - has branches
A primary alcohol will yield an _____ molecule when oxidized
Aldehyde
A secondary alcohol will yield ______ molecule when oxidized
Ketone
A tertiary alcohol will yield ____ when oxidized
No reaction
Alkene formation aka?
Intramolecular Dehydration
Ether formation aka?
Intermolecular dehydration
Alcohol react with ____ to form ester in esterification
Carboxylic acid
Methyl Alcohol other names (2)
Methanol
Wood Alcohol
Ethyl Alcohol other names (2)
Ethanol
Grain Alcohol
Component of rubbing alcohol
Ethyl alcohol
Alcohol ingridient of antifreeze for motor vehicle engines
Ethylene glycol
Alcohol unfit for beverages
Denatured alcohol
Isopropyl aka?
Isopranol
Glycerol, a component if fats aka?
Glycerin
Menthol aka?
5-methyl 2-isopropylcyclohexanol
Alcohol found in animal fats, oil
Cholesterol
Alcohol: vitamin a
Retinol
Alcohol: vitamin e
Tocopherol