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Y1S1 > MTIOCH - Finals 2 > Flashcards

MTIOCH - Finals 2 Flashcards

1
Q

Compound that resembles benzene

A

Aromatic C.

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2
Q

All aromatic c. confirm to this rule

A

Huckel Rule for Aromaticity

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3
Q

Molecular formula of benzene ring

A

C6H6

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4
Q

Iupac name of benzene

A

1, 3, 5 cyclohexatriene

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5
Q

Benzene
Melts at?
Boils at?
Density?

A

M - 55c
B - 80.1c
D - 0.88

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6
Q

Extracted from benzene

A

Nitrobenzene

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7
Q

Benzene used in drug manufacture

A

Napthalene

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8
Q

Benzene in drug manufacturing (2)

A

Aniline and phenol

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9
Q

Benzene makes a satisfactory fuel when mixed with?

A

Petrol

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10
Q

Who discovered Benzene and when?

A

1825 - Michael Faraday

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11
Q

Benzene is from?

A

Coal tar

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12
Q

Ways of extracting benzene (2)

A

Hydroforming and cyclization

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13
Q

When and who formulated the ring structure?

A

August Kekule in 1865

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14
Q

When coal is heated to _____c in the absence of air, it produces _______

A

450-1200c - Coke

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15
Q

Which are driven pff when coal is heated?

A

Coal tar

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16
Q

Give three industrial solvent under AHC

A

Benzene
Toluene
Xylene

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17
Q

AHC that is insect repellent

A

Napthalene

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18
Q

AHC connected to Anthrax

A

Anthracene

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19
Q

1/3 of our benzene supply comes from here

A

Peteoleum

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20
Q

AHC polar/nonpolar?
density ___ of water?

A

Nonpolar
Less than water

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21
Q

flame that AHC burn _______ its because of?

A

Yellow - incomplete carbon combustion

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22
Q

Cancer forming

A

Carcinogenic

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23
Q

Most have ______ the reason for the name “aroma”

A

Sweet aroma

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24
Q

AHC Halogenation Catalysts (2)

A

Iron (iii) chloride
Iron (iii) bromide

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25
Q

AHC halogenation forms?

A

Aryl Halide

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26
Q

AHC Nitration forms ____ at ____ c

A

Nitrobenzene at 50c

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27
Q

AHC Friedel-Crafts catalyst

A

Aluminum Chloride Catalyst

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28
Q

AHC Friedel-Crafts Alkylation forms? (2)

A

Alkyl benzene and hydrogen halide

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29
Q

Reagents used in side chain oxidation (2)

A

Potassium Permanganate
Potassium dichromate

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30
Q

End product of Side-Chain Oxidation

A

Benzoic Acid

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31
Q

What are the 3 Substitution Reaction

A

Halogenation
Nitration
Friedel-Crafts Alkylation

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32
Q

Which “SCO” uses Potassium Permanganate and Potassium Dichlorite

A

Side-Chain Oxidation

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33
Q

Give 4 alkyl

A

Methyl
Ethyl
Isopropyl
Sepbutyl

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34
Q

Methyl benzene (Common name and attachment)

A

Toluene
CH3

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35
Q

Hydroxybenzene (Common name and attachment)

A

Phenol
OH

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36
Q

Aminobenzene (Common name and attachment)

A

Aniline
NH2

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37
Q

Cyanobenzene (Common name and attachment)

A

Benzonitrile
CN

38
Q

Isopropylbenzene (Common name and attachment)

A

Cumene
CH3 - CH3
|
CH3

39
Q

Carboxybenzene (Common name and attachment)

A

Benzoic Acid
C - OH
|
O

40
Q

Methoxybenzene (Common name and attachment)

A

Anisole
O - CH3

41
Q

Vinylbenzene (Common name and attachment)

A

Styrene
CH = CH2

42
Q

Acetophenone

A

None
C - CH3
||
O

43
Q

Types of Disubstituted AC (2)

A

Xylene
Cresol

44
Q

Xylene positioning: 1,2
(Draw it)

A

Orthopositioning

45
Q

Xylene positioning: 1,3
(Draw it)

A

Metapositioning

46
Q

Xylene positioning: 1,4
(Draw it)

A

Parapositioning

47
Q

SN of Xylene

A

(Number) Dimethylbenzene

48
Q

Parent Name (SN2) of Xylene

A

(Number) Xylene

49
Q

CN of Xylene

A

(Letter) Xylene

50
Q

SN1 of Cresol

A

(Number a) Hydroxy - (number b) methyl benzene

51
Q

SN2 of Cresol

A

(Number) Cresol

52
Q

CN of Cresol

A

(Letter) cresol

53
Q

(3) fused ring AHC

A
  • Napthalene
  • Anthracene
  • Phenanthrene
54
Q

Character of 3 Fused Ring AHC

A

Naphtalene - 2
Anthracene - 3
Phenanthrene - 3 na tabingi

55
Q

One or more H of alipathic has been replaced with halogen atoms

A

Alkyl Halide

56
Q

One or more H of benzene ring has been replaced with halogen atoms

A

Aryl Halide

57
Q

Most alkyl halide are liquid except with ____ atoms which are gases

A

Fluorine

58
Q

Organic halides are flammable?

A

No

59
Q

OHalide that is colorless and nonirritating odor

A

Carbon Tetrachloride (CCl4)

60
Q

CCL4 is used to make?

A

Chlorofluoromethanes

61
Q

The rape liquid

A

Chloroform (CHCl3)

62
Q

Chloroform aka

A

Trichloromethane

63
Q

Iodoform aka?

A

Triiodomethane

64
Q

Halide used in Antiseptic and ointment for minor skin disease

A

Iodoform or Triiodomethane

65
Q

Halide used in aerosol cans

A

Chlorofluorocarbons or freons

66
Q

CFC means?

A

Chlorofluorocarbon

67
Q

Halide for non-stick cooking utensils

A

Polytetrafluoroethene or Teflon

68
Q

Halide used as tropical anesthetic

A

Ethyl Chloride or Chloroethane

69
Q

Give 3 inhalational general anesthetic

A

Haloethane
Isoflurane
Pesflurane

70
Q

Derivative of hydrocarbon with one or more atoms replaced by a hydroxyl

A

Alcohol

71
Q

General formula of alcohol

A

R-OH

72
Q

Recite (3) the Classification if Alcohol based in location if OH Group

A

Primary - 1
Secondary - 2
Tertiary - 3

OH group attached to has (n) carbons attached to it

73
Q

Recite (2) based on the number of OH groups present

A

Monohydroxy - OH
Polyhydroxy - OH - OH
|
C

74
Q

Recite (2) based on type of parent hydrocarbon attached to

A

Alipathic - open ended
Alicyclic - polygon

75
Q

Recite (2) based on the presence or absence of side chain other than OH group

A

Straight chain - snake
Branched chain - has branches

76
Q

A primary alcohol will yield an _____ molecule when oxidized

A

Aldehyde

77
Q

A secondary alcohol will yield ______ molecule when oxidized

A

Ketone

78
Q

A tertiary alcohol will yield ____ when oxidized

A

No reaction

79
Q

Alkene formation aka?

A

Intramolecular Dehydration

80
Q

Ether formation aka?

A

Intermolecular dehydration

81
Q

Alcohol react with ____ to form ester in esterification

A

Carboxylic acid

82
Q

Methyl Alcohol other names (2)

A

Methanol
Wood Alcohol

83
Q

Ethyl Alcohol other names (2)

A

Ethanol
Grain Alcohol

84
Q

Component of rubbing alcohol

A

Ethyl alcohol

85
Q

Alcohol ingridient of antifreeze for motor vehicle engines

A

Ethylene glycol

86
Q

Alcohol unfit for beverages

A

Denatured alcohol

87
Q

Isopropyl aka?

A

Isopranol

88
Q

Glycerol, a component if fats aka?

A

Glycerin

89
Q

Menthol aka?

A

5-methyl 2-isopropylcyclohexanol

90
Q

Alcohol found in animal fats, oil

A

Cholesterol

91
Q

Alcohol: vitamin a

A

Retinol

92
Q

Alcohol: vitamin e

A

Tocopherol

Y1S1 (31 decks)

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