lipids and fat Flashcards
examples of lipid
- Triacylglycerols (90- 95% of dietary fat)
- Cholersterols
- Sterols
- Glycolipid
- Phospholipids
Lipis
organic compounds with carbon skeletons with H & O substutuions
only dissolves in organic solvent
oils & fat
Structure of triacylglycerols
Glycerol backbone with 3 fatty acids
Fatty acid structure
long hydrocarbon chain (hydrophobic) with a carboxyl group (-COOH)(hydrophilic) one end and methyl at another end
Different form of fat structure
saturated
mono- / poly- unsaturated (cis- [bend form] ; trans- [straight form])
trans fatty acid effects on cholesterols
rasie bad LDL , lower good HDL
examples of saturated, mono- & poly- unsaturted fat
slide 12
The significance of the position of the first double bond relative to the methyl group
1) indicates the family to which the unsaturated fatty acid belongs
2) has a profound influence on their health effects and nutritional properties
essential fatty acids
organism cannot synthesize and have to be provided by the diet
linoleic acid and a-linolenic acid
animal tissues unable to introduce double bonds in positions proximal to carbon 9, counting from the methyl or N-terminus
n-3 and n-6 EFA cannot be interconverted, thereby making both essential
Omega 6 & Omega 3 structure difference
first double bond at C6
first double bond at C3
Features of essential fatty acid deficiency
- Hair loss
- Scaling dermatitis
- Increased transepidermal water loss
- Poor wound healing
- Growth retardation
- Renal failure
- Reproductive failure
EFA deficiency prevention
EFA provide at least 1-2% of TE
18: 2n-6 should provide at least 1% of TE
18: 3n-3 at least 0.2% of TE.