Fire Dynamics Flashcards
What are the four principles of FIre Science?
- Combustion
- Fire
- Heat
- Temperature
True of False. All fires involve a heat-producing chemical reaction between some type of fuel, oxidizer and combustion.
False, all fires involve a heat-producing chemical reaction between a fuel and an oxidizer. The combustion IS the chemical reaction.
What is the most common Oxidizer?
Oxygen
Are Oxidizers Combustible?
Not by themselves, but they will support combustion.
What common use do these Oxidizers have in everyday life? Calcium Hydrochlorite Chlorine gas Ammonium Nitrate Hydrogen Peroxide Methyl Ethyl Ketone Peroxide
-Cleaning pool water
-Drink water purification
-Fertilizer
-Industrial Bleaching
Catalyst in plastics manufacturing.
What is Physical Science?
Study of matter and energy
Why is it important for firefighters to understand fire dynamics?
-To be able to anticipate how the fire will behave in the future and how that affects fire operations
What is a Physical vs a Chemical change?
A Physical change is when a sustance changes forms like in size, shape, appearance but remains the same chemically. Ex: Water going from ice to liquid to gas.
A Chemical change is when a substance changes from one type of matter to another.
What is Oxidation?
A chemical reaction involving an oxidizer and another material. Rust is a slow oxidation and explosions are rapid oxidation.
What is potential energy?
The amount of energy that a substance can release in the future.
The potential energy available for release is known as the Heat of Combustion
What is potential energy?
The amount of energy that a substance can release in the future.
The potential energy available for release is known as the Heat of Combustion
What factors limit the release of potential energy?
- Chemical composition
- Arrangement
- Density of the fuel
- Availability of the oxidizer
What is Kinetic Energy?
The energy that moving objects have. In fire, the movement occurs in the movement of the molecules of the fuel.
What unit of measurement measures Energy and how is it defined?
4.2 Joules is the amount of energy required to heat 1 gram of water by 1 degree celcius.
What is the other imperial unit of energy measurement, and how does it compare to the joule?
The British Thermal Unit BTU. how much energy it takes 1 pound of water to heat up by 1 degree fahrenheit. 1,055 joules equals 1 BTU
What is an endothermic reaction?
A reaction that absorbs heat. Turning water into steam or ice into water.
What are the componants of the fire tetrahedron?
- Reducing agent (Fuel)
- Oxidizing agent
- Heat
- Chemical Chain Reaction.
Can liquids and solids burn?
Only if they are first converted to a gaseous state.
In solids it is called Pyrolysis
In liquids it is vaporization
What is the difference between Piloted ingnition and Autoignition?
Piloted ignition is when a mixture of fuel and oxygen encounter a hot enough external source to start a combustion.
Autoignition occurs one the surface of the substance is heated to a point where it ignites on its own without a spark or flame.
What is the Autoignition Temperature?
The temperature at which a substance needs to be heated in order to start self sustained combustion.
True or false. Auto ignition temperature is always lower than piloted ignition temperature.
False. It is always higher.
Can combustion occur without visible flames?
Yes
Can combustion occur without visible flames?
Yes
What are the main differences between flaming and nonflaming combustion?
Nonflaming occures at a lower temperature and burns slower. Ex: coals.
Flaming combustion is what people know as fire. It requires the perfect combination of all elements of the fire tetrahedron. Solid and liquid fuels are tranformed into gas by heating. Oxygen comes into the reaction through the inlet flow and the exhaust leaves through the outlet flow.
Why does smoke rise from the fire?
The heat causes expansion of the exhaust particles, which creates boyancy in the air surrounding it, so the particles rise.
What are the two by-products of fire?
Heat and smoke.
True or false. more people die due to exposure to heat of the fire than the toxic gases in the smoke.
False, more people die due to the toxic fumes in smoke.
What is smoke?
Product of incomplete combustion
Can smoke burn?
Yes because it is an incomplete reaction.
True or false. Less oxygen creates more smoke in a structure fire.
True. Less oxygen means more incomplete reactions.
What are the two major types of fuels in structure fires?
- Carbon-based (wood)
- Hydrocarbon (plastics)
True or false. All smoke is toxic to a certain degree
True. while some are far worse than others, it is never advised to consume smoke of any kind.
True of false. Structure fires can create both CO and CO2
True. Carbon in the air combines with the consumed oxygen to form CO and CO2
What is asphyxiation?
Death due to low oxygen levels in the blood.
What is Carbon monoxide?
The product of an incomplete combustion of carbon based materials.
True of false. Carbon Monoxide is flammable?
True, since it is an incomplete reaction, it can still burn.
How can Carbon monoxide kill people?
Levels of 0.2 % can cause unconsciousness in under 30 minutes. CO attaches to hemogloben and prevents Oxygen from attaching. too much CO can result in not enough oxygen going to the body and can cause death.
True or false. Hydrogen Cyanide is caused by complete combustion?
False. it is caused by incomplete combustion of substances that contain nitrogen and carbon.
Is HCN more or less toxic than CO?
35x more. It prevents the body from being able to use the oxygen it gathers. High concentrations can lead to death in minutes.
Is CO2 the product of complete combustion?
Yes, of organic materials
What is the unit of measurement for Pressure?
Kilopascals. The atmosphere of the earth is 101 kPa
What is the defference between Heat and Temperature?
Heat is the thermal energy needed to release the gases inside solid or liquid fuels. Heat is transfered, convectively, conductively and through radiation.
Temperature is the measurement of heat. The average kinetic energy of the particles at combustion.
True or false. Temperature is a good predictor of heat transfer.
False. Because one candle burns at the same temperature as ten candles, but the heat released by ten candles in ten times greater than the one. This increases the heat transfer.
What is the measurement of heat transfer to a unit area (Heat flux)?
Kilowatts per square meter.
What is Chemical Energy?
The most common source of heat combustion. Almost always results in production of thermal energy.
What is self-heating?
Oxidation of a substance that results in a tempertature increase from contact to Oxygen. Can lead to Spontaneous ignition.
Rags soaked in Linseed oil can self-heat to the pont that it ignites spontaneously.
What are the types of Electrical Heating?
- Resistance Heating
- Overcurrent or Overload
- Arching
- Sparking
What is Electrical Resistance Heating?
When an electric current travels through a conductor and creates heat. Lightbulbs, heaters and other appliances are designed to make use of Resistance heating.
What is Electrical Overcurrent or Overload?
When a conductor is given more electricity than it was designed to handle, it creates an excess of heat.
What is Electrical Arching?
A luminous arch of electricity that can cause heat.
What is Electrical Sparking?
When an arch occurs, hot particle can form and splatter.