Carbohydrates 2: the return Flashcards
Name the 3 important hexoses
Glucose
Galactose
Fructose
Name the 3 important disaccharides
Maltose - Glu&Glu
Sucrose - Glu&Fru
Lactose - Glu&Gal
What feature makes some sugars be called ‘reducing sugars’
Anomeric C1 can be oxidised
The anomeric carbon is the only residue that can be oxidised on these sugars
Which disaccharides are reducing sugars and which aren’t?
Maltose & Lactose are reducing sugars
Sucrose is not a reducing sugar, as it does not have an anomeric C1 that can be oxidised
What is the difference between heteropolysaccharides and homopolysaccharides
Homopolysaccharides have one monomeric species
Heteropolysaccharides have more than one monomeric species
What 2 types of glucose polymers make up starch
Amylose
Amylopectin
What is the difference between amylose and amylopectin
Amylose is straight chained and has a(1-4) linkages
Amylopectin is more abundant, and is branched.
It has a(1-6) bonds every 24 - 30 residues
How is glycogen different from starch?
Glycogen is more extensively branched than starch (amylopectin)
Much higher ‘energy density’ than starch
Glycogen is used in animals, starch is used in plants
Why is glycogen (and starch) an effective energy storage molecule?
1) Compact - lots of glucose can be stored in a small volume
2) Branched - many non-reducing ends means it can be degraded/synthesised quickly to release/store energy
3) Insoluble - osmotically inactive so does not interfere with osmotic activity
What are glycoproteins?
Class of proteins which have carbohydrate groups attached to the polypeptide chain
What effects can adding a carbohydrate to a protein have?
Increase solubility
Influence conformation/shape
Protect it from degradation
Act as communication between cells
What are Glycosaminoglycans?
also called mucopolysaccharides
Un-branched polymers
Repeating units of hexuronic acid and an amino-sugar, which alternate through the chains
Where are glycosaminoglycans mainly found?
What does this indicate about their properties?
Mucus and in synovial joints
Lubricant properties as chains easily slide over each other
What are proteoglycans?
A compound consisting of a protein bonded to mucopolysaccharide groups, present especially in connective tissue
What is the difference between glycoproteins and proteoglycans?
Glycoproteins are proteins with carbohydrates attached
Proteoglycans are GAG’s with proteins bonded to them