Vanadian chemistry Flashcards

1
Q

What is vanadium?

A

= wide range of oxidation states and colours

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2
Q

What is the oxidation state odf V+2?

A

= +2
= violet

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3
Q

What is oxidation state and colour of V3+?

A

= +3 green

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4
Q

What is the oxidation state and colour of VO2+?

A

= +4 blue

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5
Q

What is oxidation state and colour of VO2+

A

= +5 yellow

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6
Q

How can vanadium be reduced?

A

= VO2+ ions can be reduced using zinc in acidic solution, all the way to V2+ ions

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7
Q

What is the first step?

A

= VO2 + is reduced to VO2+- this is a colour change of yellow to blue
= the zinc goes from Zn to Zn2+

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8
Q

What is the second step?

A

= VO2+ is reduced to V3+ and there is a colour change of blue to green
= once again Zn goes to Zn2+

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9
Q

What is the final step?

A

= V3+ is reduced to V2+ colour change of green to violet

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10
Q

What are the trends in oxidation state for transition metals?

A

= compounds with higher oxidation states tend to be oxidisng agents

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11
Q

What are the trends in reducing agent for transition metals?

A

= low oxidation states are more likley to be reducing agents

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12
Q
A
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