Friedel crafts acylatation Flashcards
the What does this form?
= benzene to phenyl ketone
= hcl
= Alcl3
What are the reagants for this reaction?
= acyl chloride in the pressence of anhydrous chloride catalyst
What are the conditions for this reaction?
= heated under reflux and this is an electrophilic substituion reaction
What is the equation for the formation of the elecyrophile?
= AlCl3 + Ch3COcl => [Ch3CO+] + [AlCl4]-
what is the mechanism?
= the delocalised syetem in the benzene is attracted to the partial posiitve charge CO+ electrophile this forms a horse shoe shape and the bond between carbon and hydrogen breaks with the electrons going into the benzene
What is the overall equation?
= [CH3CO]+ + [AlCl4]- + benzene => phenyl ketone, Alcl3 and Hcl