Friedel crafts acylatation Flashcards

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1
Q

the What does this form?

A

= benzene to phenyl ketone
= hcl
= Alcl3

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2
Q

What are the reagants for this reaction?

A

= acyl chloride in the pressence of anhydrous chloride catalyst

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3
Q

What are the conditions for this reaction?

A

= heated under reflux and this is an electrophilic substituion reaction

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4
Q

What is the equation for the formation of the elecyrophile?

A

= AlCl3 + Ch3COcl => [Ch3CO+] + [AlCl4]-

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5
Q

what is the mechanism?

A

= the delocalised syetem in the benzene is attracted to the partial posiitve charge CO+ electrophile this forms a horse shoe shape and the bond between carbon and hydrogen breaks with the electrons going into the benzene

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6
Q

What is the overall equation?

A

= [CH3CO]+ + [AlCl4]- + benzene => phenyl ketone, Alcl3 and Hcl

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