Nitration of benzene Flashcards
What does the nitration of benzene form?
= nitrobenzene
= and a H+ ion, regenerated acid catalyst
What are the reagants for this reaction
= concentrared nitrioc acid, HNo3
= and concentrated sulfuric acid H2So4, catalyst
= electrophile:+ NO2
How is the No2+ electrophile formed?
= HNo3 + 2H2SO4 => +No2 + 2H2SO4- + H3O+
= +H-OSo2OH, reacts with a nitric acid, this has a lone pair of electrons on the oxygen, 2 , this forms a OSO2OH and a H2ONo2
= the bond between the nitrogen and oxygen breaks firming +NO2 and H2O
What is the mechanism for the nitration of benzene?
= +NO2 reacts with benzene, this forms a horse shoe shape, this must extent between 2 to 6 not any more
= the H+ breaks and electrons go to the delocalised ring
= this forms aH+ io
What is the importance of this reaction?
= synthesising useful compounds, tnt
= formation of amines, dyes
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