Transition Elements 5.3.1 Flashcards

1
Q

What is a Transition Element?

A

Elements that have one or more stable ion with partially filled d sub-shells

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2
Q

What are properties of Transition Metals?

A
High melting point
High boiling point
Denser than s-block
Conductive
Poscess strong metallic bonds
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3
Q

What happens when Transition Elements react?

A

They lose electrons from the 4s sub-shell first

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4
Q

Are Sc and Zn Transition Elements?

A

No because they don’t form ions with partially filled d sub-shells

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5
Q

What colour are Chromium ions?

A

3+:
Green
6+:
Orange (seen in dichromate)

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6
Q

What colour are Manganese ions?

A

2+:

Pink

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7
Q

What colour are Iron ions?

A

2+:
Green
3+:
Orange

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8
Q

What colour are Copper ions?

A

2+:

Blue

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9
Q

Define adsorption?

A

When something sticks to the surface of a material

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10
Q

Define absorption?

A

When something when something enters another material

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11
Q

How does Iron act as a catalyst for the Haber Process?

A

Iron offers an alternative path of reaction.

1) H2 and N2 are adsorbed onto the surface of the iron.
2) H-H and N-N bonds weaken.
3) Bonds are formed between H and N
4) Ammonia molecule desorbs from the iron

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12
Q

Examples of Catalysts and their reactions?

A

2SO3 + O2 ⇌ 2SO3
Uses V2O5 as a catalyst
Alkene +H2 → Alkane
Uses a Nickel or Platinum catalyst

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13
Q

What is a Complex Ion?

A

A Complex ion consists of a central positive ion surrounded by ligands

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14
Q

What is a Ligand?

A

A species that can donate one or more lone pairs to form diative bonds

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15
Q

What is a Co-ordination Number?

A

The number of diative bonds formed in a complex ion

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16
Q

Examples of Ligands?

A

H2O
NH3
Cl-

17
Q

What are the three types of Ligand?

A

Monodentate:
Can donate one lone pair
Bi-dentate:
Can donate two lone pairs (eg. NH2CH2CH2NH2, en)
Multidentate:
Can donate three ore more lone pairs (eg.EDTA)

18
Q

What shape are complex ions?

A

Tetrahedral
Octahedral
Square plannar

19
Q

What is Steroisomerism?

A

When two molecules have the same composition but different layout

20
Q

What are the two types of Stereoisomerism?

A

Cis:
The different ligands are next to each other
Trans:
the different ligands are opposite each other

21
Q

What is an example of a molecule with Stereoisomerism?

A

Cisplatin

It can act as a cancer drug

22
Q

What is Opticalisomerism?

A

When molecules that have the same composition.

But structures are mirrors of each other so cannot be reoientated to looke the same.

23
Q

What is a Haem group?

A

It is a complex ion within the structure of Haemoglobin

24
Q

What is the purpose of the Haem group?

A

To hold oxygen

25
Q

Why does Cyanide and Carbon Monoxide prevent a Haem group from working?

A

They react with the iron at the centre more strongly than oxygen

26
Q

What is Ligand Substitution?

A

Reversible reaction where a complex ion change some of its ligands

27
Q

What happens during the Ligand Substitution of Copper(ii)?

A

Copper and Water complex ion has a small amount of ammonia added to it, which produces copper hydroxide precipitate.
A large amount of ammonia is then added to produce a Copper with 2Waters and 4Ammonias as a complex ion.
lots of water being added returns to Copper and Water complex ion.

28
Q

What happens in the Ligan Substitution of Chromium(iii)?

A

Chromium and Water complex ion+ NaOH gives Chromium Hydroxide.
Chromium Hydroxide + Excess NaOH gives Chromium and 6 hydroxide ligands.
excess of water returns to Chromium and Water complex ion

29
Q

What is the Oxidising Agent For Fe2+ and (Cr2O7)2-?

A

(MNO4)-/H+

Acidifed Manganate

30
Q

What are Reducing Agents for Cu2+?

A

I-
Iodide
Zn/H+
Acidified Zinc

31
Q

Why is Cu+ a colourless solution?

A

It has not got any partially filled d sub-shells