Alkanes 4.1.2 Flashcards

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1
Q

What shape is the bonds around a Carbon in an Alkane?

A

Tetrahedral

109.5°

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2
Q

What is the word equation for the complete combustion of an Alkane?

A

Alkane + Oxygen → Carbon Dioxide + Water
eg.
C2H4 + 3(O2) → 2(CO2) + 2(H2O)

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3
Q

What is the word equation for the incomplete combustion of an Alkane?

A

Alkane + Oxygen → Carbon Monoxide + Water
eg.
C2H4 + 2(O2) → 2(CO) + 2(H2O)

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4
Q

What is the Cracking of a Hydrocarbon?

A

When a Long chain hydrocarbon is broken in to a short Alkane and a short Alkene

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5
Q

Why do Branchless Hydrocarbons have a higher boiling point?

A

There is greater contact area between the branchless molecules.
Therefore greater induced dipoles

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6
Q

What is Free Radical Substitution?

A

When one or more atoms within a molecule is substituted as a result of interacting witha free radical

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7
Q

What is a Free Radical?

A

Atom or Molecule with an unpaired electron

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8
Q

What are the three stages of a Free Radical Substitution?

A
Initiation:
Radicals are created
Propagation:
Radicals ar eused and regenerated
Termination:
Radicals are removed
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9
Q

What is Homolytic Fission?

A

When a bond is broken between two molecules and both retain one of the bonding electrons

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10
Q

What is an example of Initiation?

A

Cl2 → 2Cl*

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11
Q

What are examples of Propagation?

A

Cl* + CH4 → CH3* + HCl

Cl2 + CH3* → CH3Cl + Cl*

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12
Q

What are examples of Termination?

A

Cl* + Cl* → Cl2
Cl* + CH3* → CH3Cl
CH3* + CH3* →C2H6

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