Alkanes 4.1.2 Flashcards
What shape is the bonds around a Carbon in an Alkane?
Tetrahedral
109.5°
What is the word equation for the complete combustion of an Alkane?
Alkane + Oxygen → Carbon Dioxide + Water
eg.
C2H4 + 3(O2) → 2(CO2) + 2(H2O)
What is the word equation for the incomplete combustion of an Alkane?
Alkane + Oxygen → Carbon Monoxide + Water
eg.
C2H4 + 2(O2) → 2(CO) + 2(H2O)
What is the Cracking of a Hydrocarbon?
When a Long chain hydrocarbon is broken in to a short Alkane and a short Alkene
Why do Branchless Hydrocarbons have a higher boiling point?
There is greater contact area between the branchless molecules.
Therefore greater induced dipoles
What is Free Radical Substitution?
When one or more atoms within a molecule is substituted as a result of interacting witha free radical
What is a Free Radical?
Atom or Molecule with an unpaired electron
What are the three stages of a Free Radical Substitution?
Initiation: Radicals are created Propagation: Radicals ar eused and regenerated Termination: Radicals are removed
What is Homolytic Fission?
When a bond is broken between two molecules and both retain one of the bonding electrons
What is an example of Initiation?
Cl2 → 2Cl*
What are examples of Propagation?
Cl* + CH4 → CH3* + HCl
Cl2 + CH3* → CH3Cl + Cl*
What are examples of Termination?
Cl* + Cl* → Cl2
Cl* + CH3* → CH3Cl
CH3* + CH3* →C2H6