Physics II: 1-2, 11-12 Flashcards
zeroth law of thermodynamics
objects are in thermal equilibrium when they are at the same temperature
no net exchange of heat energy
a=b, b=c, then a=c
heat
transfer of thermal energy from a hotter object with higher temperature (energy) to a colder object with lower temperature (energy) until they come into thermal equilibrium (same temp)
convert C to K eq
K = C + 273
thermal expansion
describes how a substance changes in length or volume as a function of the change in temperature
linear expansion eq
ΔL = αLΔT
ΔL = change in length
α = coefficient of linear expansion
L = og length
volumetric thermal expansion eq
ΔV = βVΔT
what is the maximum distance that two objects can be from one another and still adhere to the zeroth law of thermodynamics?
no max
as long as two objects are in thermal contact and at the same temperature, they are in thermal equilibrium
isolated system
do not exchange matter or energy with surroundings
closed system
exchange energy but not matter with their surroundings
open systems
exchange both energy and matter with their surroundings
isolated system ex
bomb calorimeter
state functions
pathway independent and not defined by a process
process functions
describe the pathway from one equilibrium state to another
process function ex
work and heat
first law of thermodynamics
conservation of energy
the total energy in the universe can never decrease or increase
first law of thermodynamics eq
ΔU = Q - W
Q = energy transferred to the system as heat
ΔU > 0
when internal energy is positive, increasing temperature
ΔU < 0
when internal energy is neg, decrease temperature
Q > 0
heat flows into system
Q < 0
heat flows out of system
W > 0
work is done by the system (expansion)
W < 0
work is done on the system (compression)
according to the first law of thermodynamics, an increase in the total energy of a system is caused by…
transferring heat into the system
or
performing work on the system
according to the first law of thermodynamics, a decrease in the total energy of a system is caused by…
heat is lost from the system
or
work is performed by the system
what are the only two processes by which energy can be transferred from one object to another
work and heat
second law of thermodynamics
objects in thermal contact and not in thermal equilibrium will exchange heat energy such that the object with a higher temperature will give off heat energy to the object with a lower temperature until both objects have the same temp at thermal equilibirum
specific heat
c
amount of energy necessary to rasie one gram of a substance eby one degree C or K
specific heat of water
1 cal/gK
conduction
direct transfer of energy from molecule to molecule through molecular collisions
direct physical contact
convection
transfer of heat by the physical motion of a fluid over a material
only liquids and gases
radiation
transfer of energy by electromagnetic waves
can occur through a vacuum
heat transfer eq
q = mcΔT
q = heat gained or lost by an object
m = mass
c = specific heat
heat transfer eq when no temp change
q = mL
L = heat of transformation/latent heat of the susbtance
entropy
how much energy is spread out, or how widely spread out energy becomes in a process
change in entropy eq
ΔS = Qrev/T
Qrev = heat gained or lost in reversible process
T = temp in K
second law of thermodynamics eq
ΔSuniverse = ΔSsystem + ΔSsurroundings > 0
as the number of microstates increases, the potential energy of a molecule…
9is distributed over that larger number of microstates, increasing entropy
natural process
irreversible
what is the relationship between the entropy of a system and its surroundings for any thermodynamic process?
the entropy of a system and its surroundings will never decrease
it will always either remain zero or increase
isothermal
first law of thermodynamics reduces to:
Q = W
(bc ΔU = 0)
adiabatic
first law of thermodynamics reduces to:
ΔU = -W
bc Q = 0
isovolumetric
first law of thermodynamics reduces to:
ΔU = Q
bc W = 0
What is the difference between Heat (Q) and Specific Heat (c)?
Heat (Q) is the overall change in heat for a substance. Specific Heat (c) is the degree to which a given substance's temperature will increase based on the amount of heat added. It is the ease with which a substance will heat up.
You have 4.3 kg of water (c = 4186 J/kg⋅C; L = 2260 J/kg). How much Heat would it take to convert all of the water into vapor if the current temperature of the water is 53.7°C?
(A) 1,423
(B) 843,109
(C) 1,423,675
(D) 2,143,896
(B) 843,109
Qtotal = Qheat + Qphase Qtotal = mc∆T + mL Qtotal = (4.3)(4186)(100-53.7) + (4.3)(2260) Qtotal = (approx. 800,000 (actual: 833,390.74)) + (approx. 9,000 (actual: 9,718)) Qtotal = (approx. 809,000 (actual: 843,108.74))
CRB Which of the following statements about the 0th Law of Thermodynamics are true?
I. This establishes Temperature as a Phase Function.
II. This establishes Temperature as a fundamental property of matter
III. For Thermal Equilibrium to occur, the objects must be in contact and heat must pass.
(A) I only
(B) II only
(C) I and II only
(D) II and III only
(B) II only
Each of the following statements about the 0th Law of Thermodynamics are true:
I. This establishes Temperature as a State Function.
II. This establishes Temperature as a fundamental property of matter
III. For Thermal Equilibrium to occur, the objects must be in contact, meaning that heat is able to pass, but no heat actually will pass.
A convection oven uses heating elements to convert electrical energy to thermal energy, and then the movement of air in the oven can disperse that energy while it is pre-heating. Then, I put my meatloaf in and the air particles bombard the pan and meatloaf, increasing its temperature and cooking the meatloaf! Which mechanisms of heat transfer were used here?
I. Convection
II. Conduction
III. Radiation
(A) I only
(B) I and II only
(C) I and III only
(D) I, II and III
(B) I and II only
Convection was used when pre-heating the oven, and the heat transfer was mediated by hot air flowing away from the heating element.
Conduction was used when the air particles collided with the pan and meatloaf, increasing the temperature of the meatloaf.
Compare Heat (Q) and Temperature (T) in terms of thermal energy.
Heat is the Transfer of thermal energy between a system and its environment, whereas Temperature is the macroscopic features of having different thermal energy levels (i.e. a high temperature feeling “hot” and having high thermal energy).
Within a system, which of the following are possible?
I. Energy increases without the Surroundings changing
II. Energy is Destroyed
III. Energy is transformed from one form to another
(A) I only
(B) III only
(C) I and III only
(D) I, II and III
(B) III only
According to the Law of Conservation of Energy, Energy cannot be Created (I) nor Destroyed (II), only transformed from one form to another.
45.3 J of work is done on a certain gas, and gains 32.6 J of heat from its surroundings. By how much did its Internal Energy change?
(A) -77.9
(B) -12.7
(C) 12.7
(D) 77.9
(D) 77.9
∆U = ∆Q + ∆W ∆U = 32.6 + 45.3 ∆U = 32.6 + 45.3 ∆U = 77.9
Note that work done on a gas adds energy to the system, whereas work done by a gas subtracts energy from the system.
The area under the curve on a PV diagram is equal to what? What equation does this relate to?
The area under the curve on a PV diagram is equal to work according to the relationship W = P∆V where:
W = Work done to/by the gas. P = Pressure ∆V = Change in Volume
You look at a PV diagram and notice that the pressure increases from 12.5 atm to 34.6 atm while the Volume decreases from 55.6 L to 35.4 L. Can we use the W = -P∆V equation to solve for the work done? Explain.
No, the W = -P∆V equation cannot be used here because this equation only works for isobaric systems. Since both pressure and volume are changing here, the work could only be found by integrating or estimating the area under a PV curve on a graph.
What variables change in the ∆U = Q + W equation for each process?
(1) Isobaric
(2) Isochoric
(3) Isothermal
(4) Adiabatic
(1) Isobaric - W changes due to a change in V.
(2) Isochoric/metric/volumetric - W does not change due to Volume remaining constant.
(3) Isothermal - ∆U remains constant because T remains constant. W and Q also remain constant.
(4) Adiabatic - Q does not change. This is the definition of an Adiabatic process. The change of U is caused solely by a change in W.
how does an isothermal process look like on a P-V graph?
what is work?
hyperbolic curve
work is area under the curve
how does an adiabatic process look like on a P-V graph?
what is work?
hyperbolic curve
work is area under the curve
how does an isobaric process look like on a P-V graph?
flat line
how does an isovolumetric process look like on a P-V graph?
what is work?
vertical line
work done by gas = 0
spontaneous process
can occur by itself without having to be driven by energy from an outside source
does not necessarily happen quickly and may not go to completion
common method for supplying energy for nonspontaneous reactions
coupling nonspontaneous reactions to spontaneous ones
True or False? The Second Law of Thermodynamics states that Heat can flow from cold to hot as long as the overall heat flow is from hot to cold.
False. The Second Law of Thermodynamics states that Heat will never be seen to flow from cold to hot.
Compare the term microstate and macrostate?
A microstate is an exact arrangement/state of particles. There are often countless possible arrangements.
A macrostate is a generic state of particles. For instance, “mixed up” vs. “separated” are examples.
Why doesn’t heat ever flow from cold to hot?
Because statistically speaking there are way more microstates in which the fast moving particles and slow moving particles are mixed up.
True or false? The specific heat of a substance depends upon the phase the substance is in.
True. The specific heat of a substance depends upon the phase the substance is in.
How does Enthalpy (∆H) relate to Q?
Enthalpy (∆H) = Q
b
b
c
c
b
c
c
a
d
d
c
c
transverse waves
have oscillations of wave particles perpendicular to the direction of wave propagation (and perpendicular to direction of energy transfer)
ex: electromagnetic waves
longitudinal waves
have oscillations of wave particles parallel to the direction of wave propagation (and in the direction of energy transfer)
ex: sound waves
displacement in a wave
x
how far a point is from the equilibrium position
amplitude
A
magnitude of a wave’s maximal displacement
propagation speed of wave eq
v = fλ
period in terms of frequency eq
T = 1/f
crest
maximum point of a wave
point of most positive displacement
trough
minimum point of a wave
point of most negative displacement
wavelength
λ
distance between two crests or two troughs
frequency
f
number of cycles it makes per second
hertz
angular frequency
ω
another way of expressing frequency
radians/second
period
T
number of seconds it takes a wave to complete a cycle
inverse of frequency
angular frequency eq
ω = 2πf = 2π/T
principle of superposition
when waves interact with each other, the displacement of the resultant wave at any point is the sum of the displacements of the two interacting waves
interference
the ways in which waves interact ins pace to form a resultant wave
constructive interference
amplitude of the resultant wave = sum of the amplitudes of the two interfering waves
waves are exactly in phase with each other
destructive interference
amplitude of resultant wave = difference in amplitude between the two interfering waves
waves are exactly out of phase with each other
partially constructive/destructive interference
displacement of resultant wave = sum of the displacements of the two interfering waves
two waves are not quite perfectly in or out of phase with each other
traveling waves
have continuously shifting points of maximum and minimum displacement
standing waves
produced by the constructive and destructive interference of two waves of the same frequency traveling in opposite directions in the same space
antinodes
points of maximum oscillation
nodes
points where there is no oscillation
timbre
quality of sound
determined by natural frequency or frequencies of the object
forced oscillation
if a periodically varying force is applied to a system, the system will then be driven at a frequency equal to the frequency of the force
resonance
increase in amplitude that occurs when a periodic force is applied at the natural (resonant) frequency of an object
damping (attentuation)
decrease in amplitude by an applied or nonconservative force
how does applying a force at the natural frequency of a system change the system?
the object will resonate because the force frequency equals the natural (Resonant) frequency
the amplitude of the oscillation will increase
sound
longitudinal wave produced by mechanical disturbance of a material that creates an oscillation of the molecules in the material
sound travels fastest through…
solid with low density
sound travels slowest through…
gas with high density
within a medium, as density increases, the speed of sound ____
decreases
pitch
frequency of sound