Pd(0) with Aryl Halides Flashcards

1
Q

order of reactivity for oxidative addition

A

I>OTf>Br»Cl

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2
Q

what conditions are needed for aryl chlorides

A

electron rich and bulky ligands eg P(tBu)3, PCy3 or NHC and proper bases eg KF

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3
Q

used when

A

if aryl being coupled has halide group elsewhere on the aromatic ring

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