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B11OQ > Hydrometallation Reactions > Flashcards

Hydrometallation Reactions Flashcards

1
Q

hydroboration

A

syn addition, B adds to least sterically hindered end, H2O2 and NaOH oxidise to alcohol product

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2
Q

hydrozirconation

A

bulky Cp2Zr adds to less hindered end, syn addition, Zr substituent replaced by electrophile with retention

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3
Q

hydroalumination

A

using H-Al-iBu, Al adds less hindered end due to sterics, syn addition, Al replaced by electrophile with retention

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B11OQ (27 decks)

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