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B11OQ > General Reactions > Flashcards

General Reactions Flashcards

1
Q

oxidative addition

A

M inserted into single bond, M ON increases by 2, starting metal complex needs vacant site

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2
Q

Reactivity of leaving groups

A

I>OTf>Br»Cl

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3
Q

reductive elimination

A

concerted so ligands must be cis, bulky ligands promote dissociation

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4
Q

transmetallation reactivity

A

Zn>Sn>B>Li

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5
Q

transmetallation

A

essentially swapping of ligands with metals

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6
Q

B-hydride elimination

A

needs vacant metal coord site

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7
Q

migratory insertion

A

reverse of B-hydride elimination

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B11OQ (27 decks)

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