organic chem fuels Flashcards

1
Q

what is a fuel

A

A fuel is a substance which when burned, releases heat energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what are common fossil fuels

A

coal, natural gas and hydrocarbons (eg methane and propane which can be obtained from petroleum)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what is petroleum and how can it be made useful

A

a mixture of hundreds of hydrocarbons, as a mixture it is not very useful but upon refining (fractional distillation) its separate fractions can be very useful

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

in refining, what happens as chain length increases

A

the boiling points of compounds rise

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

once petroleum or crude oil is heated enough, how can it be collected again

A

if petroleum is heated enough, the compounds will boil to form gasses, if these rise up a tall tower they will cool as they rise and condense at different heights depending on their boiling point

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is the first fraction called? no of carbon atoms? and use for the fraction

A

refinery gas
c1 to c4
used for cooking and heating

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is the second fraction called? no of carbon atoms? and use for the fraction

A

gasoline/petrol
c5 to c6
used to fuel cars

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what is the third fraction called? no of carbon atoms? and use for the fraction

A

naptha
c6 to c10
monomer/starting point/feedstock for many chemicals and plastics

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

what is the fourth fraction called? no of carbon atoms? and use for the fraction

A

paraffin/kerosine
c10 to c15
fuel for aircraft, oil stoves and lamps

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is the fifth fraction called? chain length? uses?

A

Diesel oil
C15 to C20
fuel diesel engines

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what is the sixth fraction called? no of carbon atoms? and use for the fraction

A

fuel oil
c20 to c30
fuel for power stations, ships and home heating systems

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what is the seventh fraction called? no of carbon atoms? and use for the fraction

A

lubricating fraction
c30 to c50
oil for car engines and machinery, waxes and polishes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what is the eighth fraction called? no of carbon atoms? and use for the fraction

A

bitumen
c50+
used to make roads
IS SOLID

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what happens as chain length increases

A

viscosity increases, boiling point increases
flammability and volatility decrease

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

where does refinery gas condense and as chain length increases where do the gasses condense

A

refinery: at the top of the fractionating tower
as chain length increases, the gasses condense lower in the fractionating tower

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what do the properties of each fraction dictate

A

the properties dictate the uses

17
Q

why is petrol/gasoline best suited for fuel in cars

A

this fraction is thin, runny, volatile and highly flammable which is suitable for burning in car engines; where the fuel must catch fire with just a spark

18
Q

why is fuel oil best suited for fuel in ships

A

this fraction is thicker and much less volatile, this suits ships and furnaces where a volatile fraction might cause an explosion

19
Q

what is bitumen mixed with and why is it ideal for road building

A

bitumen is a soft solid that does not burn until over 200 degrees celsius
it is mixed with stone chips when melted

20
Q

upon further refinery what is found in refinery gas (fraction 1)

A

methane, ethane, propane and butane

21
Q

what must be removed from the liquid fuel fractions and why

A

sulfur as sulfur burns to give sulfur dioxide which causes acid rain

22
Q

What type of reaction is burning fuels

endo or exo

A

combustion reaction

exo

23
Q

What are the 2 types of combustion reaction
conditions for both
Products

A

Complete combustion - sufficient oxygen supply - co2 and h20

incomplete - insufficient oxygen supply - CO (carbon monoxide

24
Q

What are the 2 types of combustion reaction
conditions for both
Products

A

Complete combustion - sufficient oxygen supply - co2 and h20

incomplete - insufficient oxygen supply - CO (carbon monoxide