Chapter 11 Acids and Bases - Oxides + Neutralisation Flashcards

1
Q

What is neutralisation

A

reaction with between alkali and acid that gives water and salt

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2
Q

Where does water come from in neutralisation

A

The hydrogen ions from the acid and the hydroxide ions from the alkali give water molecules

H+ + OH- —> H2O

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3
Q

How does an acid donate protons
How are the protons accepted
what are formed

A

The H+ ion of an acid is essentially just a proton (no electrons)

This is donated to the Hydroxide ion.

The hydroxide ions accept the proton to form water molecules

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4
Q

pH and colour of a neutral substancew

A

pH: 7
colour: green

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5
Q

Real life application of neutralisation

A

Acidity in soil:

Optimal plant growth requires a soil pH between 5 and 8. Soil pH imbalance to be too acidic reduces plant growth yield. Soil acidity is neutralized by adding lime or powdered limestone.

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6
Q

What are oxides

A

Compounds containing oxygen and another element

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7
Q

How are basic oxides formed

A

In general, metals react with oxygen to form basic oxides

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8
Q

What can basic oxides do

A

They can neutralize acids

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9
Q

How are acidic oxides formed

A

Non-metals react with oxygen to form acidic oxides

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10
Q

What happens when the acidic oxides are dissolved in water

A

they give acids

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11
Q

what are amphoteric oxides

define them

A

amphoteric oxides act as acids and bases.

when presented with an acid they act as a base but when presented with a base they act as an acid

definition: they can NEUTRALISE both acids and alkakis

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12
Q

Amphoteric oxide examples

A

Al2O3
ZnO

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13
Q

what are neutral oxides

A

neutral oxides are neither basic nor acidic

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14
Q

examples of neutral oxides

A

1) Nitrous oxide (N2O)

2) Nitric oxide (NO)

3) Carbon monoxide (CO)

4) Water (H2O)

5) Manganese(IV) oxide (MnO2)

6) Hydrogen peroxide (H2O2)

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15
Q

How to prove that an oxide is amphotheric

A

Show that the oxide reacts with both an acid and a base to give —> salt + water

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16
Q

Word and Chem Eqns to prove Al2O3 is amphoteric

A

with acids:
Aluminium Oxide + Hydrochloric acid —> Alumium Chloride + Water
Al2O3 + 6HCl —> 2AlCl3 + 3H2O

with alkali:
Alumium Oxide + Sodium Hydroxide —> Sodium Aluminate + Water
Al2O3 + 6NaOH —> 2Na2AlO3 + 3H2O

17
Q

Word and Chem Eqns to prove ZnO is amphoteric

A

with acids:
zinc oxide + hydrochloric acid —> zinc chloride + water
ZnO + 2HCl —> ZnCl2 + H2O

with alkali:
zinc oxide + sodium hydroxide —> sodium zincate + water
ZnO + 2NaOH —> Na2ZnO2 + H2O

18
Q

if a question states how we could show a compound is an acid without using an indicator what to do

A

add metal
hydrogen is given off/effervescence
burning splint pops

19
Q

what problem arises when a compound of a transition element doesn’t include its oxidation number? eg iron oxide

A

because they have more than one oxidation state, form ions with different charges.
fe2+ and fe3+

20
Q

what does saturated solution mean

A

A state of a solution where no more solute can be dissolved in the solution at that given temperature.

21
Q

What kind of oxide is Calcium Oxide

Process to make it

name colours if any

A

Basic oxide

heat calcium up
plunge it into a gas jar with oxygen

bursts into an INTENSE WHITE FLAME WITH A TINGE OF RED

and leaves white ash which is calcium oxide

22
Q

Chemical reaction for making calcium oxide

A

2Ca (s) + O2 (g) —-> 2CaO (s)

23
Q

What kind of oxide is Iron (III) oxide

Process to make it

name colours if any

A

Basic oxide

Heat iron wool
plunge into a jar of oxygen
glows bright and throws out a shower of bright orange sparks

BLACK solid left behind is iron (iii) oxide

24
Q

Chemical equation of making iron (III) oxide

A

4Fe (s) + 3O2 (g) —-> 2Fe2O3 (s)

25
Q

What kind of oxide is Copper (II) oxide

process to make

A

basic

Copper ‘turnings’ are heated and then a stream of oxygen passes over it

surface turns BLACK which is Copper (II) oxide

26
Q

Why is the process to make copper (II) oxide different

how are reactivity and oxygen related

A

Copper too unreactive to catch fire in oxygen

the more reactive the metal is the more vigorously it reacts with oxygen

27
Q

Chemical eqn to make copper (II) oxide

A

2Cu (s) + O2 (g) —> 2CuO (s)

28
Q

What kind of oxide is carbon dioxide

Process to make it

name colours if any

A

Acidic oxide

Powdered carbon heated over bunsen burner until RED-HOT

plunged into a jar of o2

glows bright RED and forms CO2 gas

29
Q

Chemical eqn for formation of Carbon Dioxide

A

C (s) + O2 (g) —> CO2 (g)

30
Q

What kind of oxide is Sulfur Dioxide

Process to make it

name colours if any

A

Acidic oxide

Sulfur catches fire over a bunsen burner

burns with a BLUE flame

(burns even brighter in pure oxygen)

forms a gas - sulfur dioxide

31
Q

Chemical eqn to form sulfur dioxide

A

S (s) + O2 (g) —> SO2 (g)