Chapter 7 Electrolysis Flashcards

1
Q

How does electricity travel

A

Negative to positive

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2
Q

What is a conductor

A

a substance that allows electricity to pass through

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3
Q

What is an insulator

A

A substance that doesn’t let electricity pass through

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4
Q

Why can conductors conduct

A

Because they have free electrons

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5
Q

What are the solid conductors

A

Carbon (graphite)
Metals

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6
Q

What is decomposition

A

The breaking down of a compound

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7
Q

What is electrolysis

A

The decomposition of an ionic compound, when molten or in aqueous solution, by passing electric current.

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8
Q

What is an electrolytic cell

A

The entire set up of apparatus in electrolysis

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9
Q

What is the positive electrode called
What is the Negativeelectrode called

A

Anode (+)
Cathode (-)

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10
Q

What is the electrolyte

A

The liquid that undergoes electrolysis

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11
Q

Which electrodes are inert electrodes

A

Platinum
Carbon

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12
Q

What are inert electrodes

A

Electrodes that remain unchanged, but can carry current.

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13
Q

Why does decomposition occur

A

Electrons flow from negative to positive

In the liquid, ions carry the current. The ions move to the electrode of opposite charge hence current is transferred between electrodes through the solution.

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14
Q

Which ion moves to which electrode and what is carried out there

A

Cations - Cathode - Reduction

Anions - Anode - Oxidation

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15
Q

What are the 4 poss substances (reactivity series)that form at the cathode in the electrolysis of an aqueous solution and why?

A

Hydrogen (H)
Copper (Cu)
Silver (Ag)
Gold (Au)

They are less reactive.

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16
Q

At anode what forms in a dilute solution and half equation

A

Oxygen would form

4OH- —-> 2H2O + O2 + 4e

17
Q

Half equation for water

A

H20 —> H+ + OH-

18
Q

At anode what forms in a concentrated halide solution
and the three halides that could form

A

The halogen forms
Bromine
Iodine
Chlorine

19
Q

What if there is no halide in the solution, then what forms

A

Oxygen

20
Q

What does RAC stand for

A

Reduction At Cathode

21
Q

Other uses of electrolysis

A

Metal refining
electroplating

22
Q

What is electroplating

A

Using electricity to coat one metal with another to make it look better or prevent corrosion.

23
Q

General set up for electroplating (cathode, anode, electrolyte)

A

Cathode - Object to be electroplated
Anode - Metal X
Electrolyte - A solution of soluble compound X

24
Q

in which solution do halogens get discharged

A

concentrated

25
Q

in a refining which electrode has the pure metal

A

negative electrode
cathode

26
Q

in a refining which electrode has the impure metal

A

positive electrode
anode

27
Q

which types of elements go to the cathode

A

metals and hydrogen to get reduced

28
Q

which types of elements go to the anode

A

non-metals to get oxidised

29
Q

how can we use electrolysis to determine which metal is more reactive between 2 metals e.g manganese or magnesium

A

set up a magnesium/ manganese cell
the electrode that loses mass is more reactive

30
Q

how do electrons flow

A

negative to positive

31
Q

Explain, in terms of electron transfer, why the more reactive metal is always the negative
electrode.

A

metals react by losing electrons
the more reactive metal will lose electrons more readily (making the electrode negatively charged)

32
Q

in conc aqueous what comes at anode

A

halogen

33
Q

How are electrons carried across the cell

> wires and electrodes
solution

A

wires and electrodes - electrons
solution - ions