Module 5 Flashcards
The temperature of a gas depends on its average _____ energy
Kinetic
Increased pressure of a gas = ______ volume
decreased
Boyle’s Law
Volume is inversely related to pressure with a gas
Law that explains pressure gradient in lungs during respiration
Boyle’s Law
As pressure of a gas decreases, volume _______
Increases
Pressure and volume of a gas are ______ proportional
inversely
P1V1 = P2V2
Boyle’s Law
At 36 Degrees Celcius,
Vt is 500mL @ sea level
What is Vt @ 730mmHg?
500(760) = V2(730)
500(760)/730 = V2
so,
520mL
Volume of a gas is _____ proportional to its absolute temperature when pressure and amount of gas are constant (flexible container)
Directly
Charles’ Law
Volume of gas and temperature are directly proportional
As temperature of a gas increases, volume _____
increases
V1/T1 = V2/T2
Charles’ Law
When performing gas calculations, temperature must be converted to ______
Kelvin
Volume of a gas _______ when heated
Increases
When a pt is febrile, what do you need to watch for with their ETT?
Increase in cuff volume
At sea level,
balloon w/ helium contains 200mL in 19 degree C room,
Volume @ 38 degrees C?
200/292 = V2/311
(200/292)(311) = V2
so,
213mL
At a constant volume (rigid container), the pressure of a gas is _____ proportional to the temperature
Directly
At constant volume (rigid container), as temperature increases, pressure ______
increases
Does Gay-Lussac’s Law pertain to gas in a rigid or flexible container?
Rigid
Does Charles’ Law pertain to gas in a rigid or flexible container?
Flexible
P1/T1 = P2/T2
Gay-Lussac’s Law
Full cylinder of O2 has 2200psi in 20 degrees C,
What is the pressure in 32 degrees C?
2200/293 = P2/305
(2200/293)(305) = P2
so,
2290psi
What is the number of molecules in 1 mole of gas?
6.023x10^23
Avogadro’s number is ______?
6.023x10^23
Avogadro’s hypothesis?
1 mole of any gas @ STP (standard temperature pressure) occupies a volume of 22.4L
How much volume does 1 mole of gas occupy?
22.4L
Avogadro’s Law
Volume of gas is directly proportional to the number of gas molecules at STP (standard temperature pressure)
Quantity of gas is expressed in _____ units
mole
V1/n1 = V2/n2
Avogadro’s Law
What volume does 2 moles of N2O occupy at STP?
- 4L x 2 =
44. 8L
Balloon has 1.9L of 0.0920 mol of helium,
0.0210 mol of helium is added,
What is new volume of balloon?
1.9/0.092 = V2/0.113
(1.9/0.092)(0.113) = V2
so,
2.33L
This theory was created to explain the ideal gas law
Kinetic Molecular Theory
Combination of the empirical gas laws
Ideal Gas Law
Name the three empirical gas laws
Boyle’s Law
Charles’ Law
Gay-Lussac’s Law
Ideal Gas Law equation
PV=nRT
Pressure)(Volume)=(moles)(Gas constant)(Temp
Gas constant for Ideal Gas Law
0.0821 atm/K/mol
5g of neon at 256mmHg & 35 degrees C
What is the volume?
256mmHg = 0.3368atm
5g Ne = 0.25mol (1mol of Ne = 20.1797)(molecular weight)
35C = 308K
0.3368(V) = 0.25(0.0821)(308)
so,
19L
_________ equation corrects the Ideal Gas Law & accounts for molecular volume and molecular interactions in a gas
Van der Waal’s Equation
Dalton’s Law of Partial Pressure
Total pressure = sum of each gas’ partial pressures
Approximate percent of O2 in RA @ sea level?
21%
Approximate percent of N2 in RA @ sea level?
79%
Partial pressure of O2 at sea level?
0.21 x 760 = 160mmHg
Partial pressure of N2 at sea level?
0.79 x 760 = 600mmHg
Dalton’s Law of Partial Pressure equation
Pt = P1 + P2 + P3 + P4 + …..
What are the partial pressures of N2O & O2 if they are delivered in a 70/30% mixture at sea level?
PN2O = 0.70(760) = 532mmHg PO2 = 0.3(760) = 228mmHg
At STP, what is the partial pressure of O2 if the fresh gas flow from the anesthesia machine is 50/50% air/O2 mixture?
PO2 = 0.50(760) = 380mmHg Pair = 0.50(760) = 380mmHg but, PO2 in air = 0.21(380) = 79.8mmHg so,
380 + 79.8 = 459.8mmHg
This process explains why it is important to slowly open gas cylinders and pipes
Adiabatic Process
Opening a cylinder fast = adiabatic process or not?
Yes, adiabatic process
Opening a cylinder slowly = adiabatic process or not?
No, not an adiabatic process (has time to equilibrate)
Joule-Thompson Effect
Rapid expansion of gas causes the temp to decrease
This effect happens when you rapidly open a gas valve
Joule-Thompson effect