energetics Flashcards

1
Q

why is it important top know energy values

A

to measure the energy values of fuels
to calculate the energy requirements for industrial processes
• it helps to predict whether or nor a reaction will take place.

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2
Q

what is Thermochemistry

A

the study of heat changes during chemical reactions.

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3
Q

what happens in chemical reactions

A

When a chemical reaction takes place, chemical bonds break and
new ones are formed.

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4
Q

what is an endothermic reaction

A

if energy has been taken in at the end of the reaction

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5
Q

what is an exothermic reaction

A

if energy has been given out, the reaction is exothermic at the end of the reaction,

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6
Q

what does the quantity of energy depends on

A

The amount of heat given out or taken in during a chemical
reaction depends on the quantity of reactants. This energy is usually
measured in kilojoules per mole, kJ mo1- 1•

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7
Q

what do you need to do to find the quantity

A

To avoid any confusion

about quantities you need to give an equation.

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8
Q

Enthalpy change,

A

When you measure a heat change at constant pressure,

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9
Q

what are the standard conditions for enalpy change

A
  • pressure of 100 kPa

* temperature of 298K

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10
Q

what else affects enalphy change

A

The physical states (gas, liquid, or solid) of the reactants and products

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11
Q

gas vs liquid products

A

For example, heat must be put in to change liquid to gas and is given out when a gas is
changed to a liquid. This means that you must always include state
symbols in your equations.

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12
Q

steam vs liquid

A

gaseous water has a Lower exothermic level than liquid water as energy must be applied to break hydrogen bonds in order for water to become a gas

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13
Q

enthalpy diagram

A

The vertical axis represents enthalpy, and the horizontal axis, the extent
of the reaction.

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14
Q

The standard molar enthalpy of formation

A

is the enthalpy change when one mole of substance is formed from its constituent elements under standard conditions. all reactants and products being in their standard states.

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15
Q

how is temperature measured

A

Heat and temperature
Temperature is related to the average kinetic energy of the particles
in a system. As the particles move faster, their average kinetic energy
increases and the temperature goes up. But it doesn’t matter how
many particles there arc. temperature is independent of the number
present. Temperature is measured with a thermometer.

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16
Q

measuring heat change

A

Heat is a measure of the total energy of all the particles present in
a given amount of substance.

17
Q

so does a lukewarm bath or a red hot nail have the most heat energy

A

So a bath
of lukewarm water has much more heat than a red hot nail because
there are so many more particles in it.

18
Q

what does heat rely on

A

It does depend on how much of the substance is present The energy of every particle is included.

19
Q

how to Measure the enthalpy change of a reaction

A
  1. mass of the substance that is being heated up or cooled down
    2 temperature change
    3 specific heat capacity of the substance.
20
Q

specific heat capacity definition

A

the amount or heat needed to raise the temperature of Jg of substance by I K.

21
Q

specific heat capacity definition

A

the amount or heat needed to raise the temperature of 1g of substance by I K.

22
Q

The simple calorimeter

A

q = m c :. T