energetics Flashcards
why is it important top know energy values
to measure the energy values of fuels
to calculate the energy requirements for industrial processes
• it helps to predict whether or nor a reaction will take place.
what is Thermochemistry
the study of heat changes during chemical reactions.
what happens in chemical reactions
When a chemical reaction takes place, chemical bonds break and
new ones are formed.
what is an endothermic reaction
if energy has been taken in at the end of the reaction
what is an exothermic reaction
if energy has been given out, the reaction is exothermic at the end of the reaction,
what does the quantity of energy depends on
The amount of heat given out or taken in during a chemical
reaction depends on the quantity of reactants. This energy is usually
measured in kilojoules per mole, kJ mo1- 1•
what do you need to do to find the quantity
To avoid any confusion
about quantities you need to give an equation.
Enthalpy change,
When you measure a heat change at constant pressure,
what are the standard conditions for enalpy change
- pressure of 100 kPa
* temperature of 298K
what else affects enalphy change
The physical states (gas, liquid, or solid) of the reactants and products
gas vs liquid products
For example, heat must be put in to change liquid to gas and is given out when a gas is
changed to a liquid. This means that you must always include state
symbols in your equations.
steam vs liquid
gaseous water has a Lower exothermic level than liquid water as energy must be applied to break hydrogen bonds in order for water to become a gas
enthalpy diagram
The vertical axis represents enthalpy, and the horizontal axis, the extent
of the reaction.
The standard molar enthalpy of formation
is the enthalpy change when one mole of substance is formed from its constituent elements under standard conditions. all reactants and products being in their standard states.
how is temperature measured
Heat and temperature
Temperature is related to the average kinetic energy of the particles
in a system. As the particles move faster, their average kinetic energy
increases and the temperature goes up. But it doesn’t matter how
many particles there arc. temperature is independent of the number
present. Temperature is measured with a thermometer.