A2 Electrochemistry Flashcards

1
Q

redox reaction

A

the transfer of electrons

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2
Q

the flow of electrons

A

is electrical current

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3
Q

oxidation

A

electrons are lost

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4
Q

reduction

A

electrons are gained

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5
Q

what happens in half cells

A

electrons flow between half cells.

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6
Q

what do half cells have

A

two different elements in different oxidation states

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7
Q

electrode

A

the part of the cell where electrons flow in and out from

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8
Q

what happens during oxidation

A

metal oxidises and ions are reduced

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9
Q

half cell equation direction

A

it shows a reduction reaction where an ion forms a metal

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10
Q

how can be gas be used in a redox electrochemical experiment?

A

the gas is bubble in the solution. the electrode used is platinum

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11
Q

why is a metal electrode used for gases?

A

to give it a surface to react on

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12
Q

why use platinum

A

it is inert
it is solid
it can conduct electricity

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13
Q

explain what happens in a gas one

A

chlorine gas passes through a glass tube
the glass tube is at 100kpa and 298k and 1 mol
there are cl-.
the chlorine ions are oxidised and chlorine gas is reduced,
it is a dynamic equilibrium as the forward and backwards reaction are at the same rate and constant concentration,

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14
Q

metal electrodes

A

metals surrounded by its solution

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15
Q

gas electrodes

A

gas in its aqeous solution

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16
Q

Redox electrode

A

two different ions of the same elements

17
Q

how to measure the potential of an electrode

A

the actual potential of the cell cannot be measured directly.
add another half cell with known potential, measure the potential difference and subtract from known potential

18
Q

electrochemical cell

A

two half cells

19
Q

SHE

A

standard hydrogen electrode potential difference of 0 acts as a universal reference .
the standard which we compare the other potentials to.

20
Q

how to set up electrochemical cell

A
  1. The metals are joined by a wire
  2. a piece of paper soack in concentrated kno3 is dipped in the solution to form a salt bridge
    3, voltmeter
21
Q

salt bridge

A

paper soaked in unreactive ions

agar

22
Q

why use a high restitance voltmeter

A

to measure how hard electronsa re being pushed

to measure the potential of the electron flow

23
Q

standard electron potential

A

the emf that is generated when connected to a standard hydrogen electrode in 298k, 100kpa and 1 mol dm-3

24
Q

emf

A

how much force electrons are pushed asround the circuit

25
Q

reducing cell

A

cathode

26
Q

oxidising cell

A

anode

27
Q

what way to electrons slow

A

negative to postitive - there is a force of attraction