A2 Electrochemistry part2 Flashcards
types of cells
rechargeable, non rechargable fuel cells
cell advantages
are portable
battery definition
one or more cell
cheap cells
the chemicals are used up in the cell
this causes the voltage/ potential to fall to 0.00 so no electrons flow. so no electricity
rechargeable batteries
the reaction is reversible when you apply an external current to regenerate the current
fuel cell
fuel cells have a continous supply of chemicals so they do not get used up /or need to be applied with an external current ish
acidic hydrogen fuel
h2 === > 2h+ 2e- anode negative
o2 + 4e- + 2h+======> 2h20 cathode positive
alkali
h2 + oh- =====> h20 + 2e- anode negative
o2 + h20 + 4e- =======>4 oh- + vcahtode positive
what happens to the hydrogen ions
the hydrogen ions move in the electrolyte from a high concentration of protons to a low concentration.
what are oxidising agents?
gains electrons
why is KCL inappropriate
cl- ions react to form a precipitate with a sliver
what happens
Fe is oxidised to Fe 111 ions
what happens when equilibrium shifts left
the electrode potential becomes more positive
why is the emf value constant for the fuel cells
the reactants are constantly added in the cell so the concentration remains constant