A2 Optical isomerism Flashcards
optical isomerism
when 4 functional groups are attached to the chiral centre which results in mirror image non-identical non-superimposable isomer
structural isomerism
different functional group
different chain
different position of functional group
stereoisomerism
they have the same structural formula but atoms are arranged differently across the plane
types of stereoisomerism
E Z isomerism
optical isomerism
optical isomerism and plane polarised light
optical isomers can rotate plane polarised light in opposite anticlockwise vs clockwise
chiral
carbon is bonded to four different groups and is not symmetrical
optical isomers name
enantiomers
ordinary light goes
all directions
what happens if light passes through a polaroid
light vibrate on a vertical plane
polarised light
there are equal conc and volume of optical isomers, this is causes light to rotate one direction and one the other,
racemates
contains equal quantities of optical isomers
it does not show any optical activity
as isomers cancel rotation effect of each other