A2 Optical isomerism Flashcards

1
Q

optical isomerism

A

when 4 functional groups are attached to the chiral centre which results in mirror image non-identical non-superimposable isomer

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2
Q

structural isomerism

A

different functional group
different chain
different position of functional group

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3
Q

stereoisomerism

A

they have the same structural formula but atoms are arranged differently across the plane

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4
Q

types of stereoisomerism

A

E Z isomerism

optical isomerism

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5
Q

optical isomerism and plane polarised light

A

optical isomers can rotate plane polarised light in opposite anticlockwise vs clockwise

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6
Q

chiral

A

carbon is bonded to four different groups and is not symmetrical

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7
Q

optical isomers name

A

enantiomers

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8
Q

ordinary light goes

A

all directions

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9
Q

what happens if light passes through a polaroid

A

light vibrate on a vertical plane

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10
Q

polarised light

A

there are equal conc and volume of optical isomers, this is causes light to rotate one direction and one the other,

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11
Q

racemates

A

contains equal quantities of optical isomers
it does not show any optical activity
as isomers cancel rotation effect of each other

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