A2 PH - DEFINING ACIDS ] Flashcards
The Brnnsted-Lowry description of acidity
An acid is a molecule which donates a proton and a base accept the base
Monoprotic Acid
donates one proton
Diprotic acid
donates 2 protons
Water can act as
a base and a acid
H3O +
H30 + is called the oxon ium ion, but the names hydronium ion and
hydroxonium ion are also used.
Why is H+ Called a proton
it has lost a electron, therefore this means that it only has a proton in the nucleus as no neutrons are present
since there is no electrons they can never give electrons only accept electrons
Water is slightly ionised:
This means it existed as this in equilibrium
H20(l) .- H+(aq) + oH-(aq)
It can also be written in the form
H20(l) + H20(1) …- H 30•(aq} + OH-(aq)
Kw
The equilibrium constant, Kw, is called the dissociation constant or ionization constant of water.
In pure water what is The Kw constant
1.00x10-7 M.
More kw
Kw is called the ionic product of water and at 298k it is equal to
1.0 x 10-14 mol 2 dm-6 • Each H20 that dissociates (splits up) gives rise
to one H+ and one oH- so. in pure water, a t 298 K :
why is water always at a constant
Because equilibrium lies to the left a lot there is a small value of ions so water is at a constant
at 298k water
it is 1 x 10-14
what is the Ph value since dissociation is one to one
h+ is 1 x10-7
so Ph is 7 in pure water - our interpretation of neutral
at 373k water
it has a Ph of 6.14
it appears acidic
the charges balance out so it is neutral Ph
the neutral point has changed.
What does a proton exist as
the proton does not exist in itself but rather it interacts with water to form H30+