Chem5 - Phases Flashcards

1
Q

at constant pressure heat =

A

enthalpy

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2
Q

what is standard temperature and pressure?

A

0 Celsius/273 K, 1atm

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3
Q

what are the characteristics of an ideal gas?

A

molecules have no size or volume, do not exert a force on eachother, have compeletely elastic collisions, and the average KE of each molecule=the temperature

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4
Q

what is the ideal gas law equation?

A

PV=nRTP is pressure in atmV is volume in Ln is molsR is constant, .08206 or 8.314T is temp in Kelvin

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5
Q

how does a simple mercury barometer work?

A

tube of mercury closed at one end and inverted into bath of mercury, height changes depending on force of atmospheric pressure

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6
Q

what is 1atm equal to?

A

1atm=760torr/760mmHg

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7
Q

what is Boyle’s law?

A

PV=constant

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8
Q

what is charles’ law?

A

V/T=constantgas volume is directly proportional to temperature

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9
Q

what is avogadro’s law?

A

V/n=constantat constant temp and pressure, gas volume is directly proportional to # of mols

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10
Q

at STP, 1 mol of gas occupies

A

22.4 L

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11
Q

how do calculate mol fraction?

A

of mols of gas divided by total # of mols of gas

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12
Q

what is Dalton’s law?

A

Ptotal=P1+P2+P3…

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13
Q

how to calculate partial pressure?

A

total pressure of mixture * mol fraction of the gas you are trying to calculate partial pressure for

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14
Q

when do gases deviate from ideal behavior?(real gases)

A

high pressure and low remperature, (molecules forced close together)

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15
Q

what does the van der waals equation do?

A

approximates real pressure/volume by actually accounting for the molecular mass/complexity of each molecule

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16
Q

what does the van der waals equation state?

A

Vreal>Videal and Preal<Pideal

17
Q

what is the definition of heat capacity?

A

added energy required to increase temperature of a substance by 1 kelvin

18
Q

what is the equation for heat capacity?

A

C=q/ΔT

19
Q

1 calorie(cal)=

A

4.18Jamount of energy required to raise 1g H2O by 1 degree Celsius

20
Q

1 Calorie (from food label)

A

=1000calories=4184 Joules

21
Q

what is the equation for specific heat capacity?

A

q=mcΔT

22
Q

what is the equation for heat transfer?

A

q=CΔT

23
Q

what does a coffee cup calorimeter do?

A

measures reaction at CONSTANT PRESSURE

24
Q

what does a bomb calorimeter do?

A

measures at a CONSTANT VOLUME

25
Q

what does heat of fusion refer to?

A

melting

26
Q

what does heat of vaporization refer to?

A

boiling

27
Q

melting, vaporization, and sublimation all have a ___ enthalpy sign

A

positive

28
Q

freezing, condensation, and deposition all have a __ enthalpy sign

A

negative

29
Q

what is the critical point?

A

composed of critical temp (temp at which it cannot liquefy any further)+critical pressure. any point above that is the supercritical fluid.

30
Q

how does a venturi mask work?

A

decreased pressure inside mask allows air to rush in because its pressure is greater