Chem5 - Phases Flashcards
at constant pressure heat =
enthalpy
what is standard temperature and pressure?
0 Celsius/273 K, 1atm
what are the characteristics of an ideal gas?
molecules have no size or volume, do not exert a force on eachother, have compeletely elastic collisions, and the average KE of each molecule=the temperature
what is the ideal gas law equation?
PV=nRTP is pressure in atmV is volume in Ln is molsR is constant, .08206 or 8.314T is temp in Kelvin
how does a simple mercury barometer work?
tube of mercury closed at one end and inverted into bath of mercury, height changes depending on force of atmospheric pressure
what is 1atm equal to?
1atm=760torr/760mmHg
what is Boyle’s law?
PV=constant
what is charles’ law?
V/T=constantgas volume is directly proportional to temperature
what is avogadro’s law?
V/n=constantat constant temp and pressure, gas volume is directly proportional to # of mols
at STP, 1 mol of gas occupies
22.4 L
how do calculate mol fraction?
of mols of gas divided by total # of mols of gas
what is Dalton’s law?
Ptotal=P1+P2+P3…
how to calculate partial pressure?
total pressure of mixture * mol fraction of the gas you are trying to calculate partial pressure for
when do gases deviate from ideal behavior?(real gases)
high pressure and low remperature, (molecules forced close together)
what does the van der waals equation do?
approximates real pressure/volume by actually accounting for the molecular mass/complexity of each molecule