CHEM KINETICS FORMULAS Flashcards

1
Q

ZERO ORDER

Slope of the line (m)

A

(π‘š) = 𝐢2 βˆ’ 𝐢1 / 𝑑2 βˆ’ 𝑑1

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2
Q

ZERO ORDER

Rate constant (k)

A

(π‘˜) = βˆ’(π‘š)

usual unit = mg/mL/hr
mg mL-1 hr-1

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3
Q

ZERO ORDER formula

A

C = (-k)(t) + Cβ‚€

k = rate constant
t = time
Cβ‚€ = initial concentration

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4
Q

ZERO ORDER

Half-life (t1/2)

A

𝑑1/2 = 0.50(𝐢₀) / π‘˜

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5
Q

ZERO ORDER

Shelf-life (t90)

A

𝑑90 = 0.10(𝐢₀) / π‘˜

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6
Q

FIRST ORDER

Slope of the line (m)

A

(π‘š) = ln𝐢2 βˆ’ ln𝐢1 / 𝑑2 βˆ’ 𝑑1

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7
Q

FIRST ORDER

Rate constant (k)

A

(π‘˜) = βˆ’(π‘š)

usual unit = hr-1

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7
Q

FIRST ORDER

Half-life (t1/2)

A

𝑑1/2= 0.693 / π‘˜

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8
Q

FIRST ORDER

Shelf-life (t90)

A

𝑑90 = 0.105 / π‘˜

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9
Q

b (y intercept) is also the same with

A

Cβ‚€ = initial concentration

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10
Q

ZERO ORDER

b (y intercept) / Cβ‚€

A

Cβ‚€ = Cβ‚‚ + (π‘˜)(𝑑₂)

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11
Q

FIRST ORDER

b (y intercept) / lnCβ‚€

A

lnCβ‚€ = ln𝐢2 + (π‘˜)(𝑑₂)

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