Chem Exam 1 Flashcards

1
Q

Quantum Numbers

A

tell us where to find electron in an atom (orbital and spin)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Principle Quantum Number

A

symbol: n
tells us the electrons energy level
the bigger the n value, the higher the energy level

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Azimuthal Quantum Number

A

symbol (L)
Shape of the space where we might find electron

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Magnetic Quantum #

A

symbol (ml)
Tells you orientation of orbital
when L = 0 there is only one possible orientation for

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Spin Quantum #

A

(ms)
tells you the spin (up or down)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Electron Configuration

A

how electrons fill up the orbitals

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Aufbau Principle

A

rule book for how electron configuration is filled
–> fill orbitals in order of increasing energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Hund’s Rule

A

when filling up orbitals that have the same energy level, they will each occupy their own before doubling up

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

orbitals

A

0 = s
1 = p
2 = d
3 = f

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Element Written

A

X = element
A = atomic mass #
Z = atomic #

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Mass measured in

A

grams (g)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Volume measured in

A

liter (L) or cubic centimeter (cm3)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Amount measured in

A

atoms
molecules
moles

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Temperature

A

Celcius (C)
Kelvin (K)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Energy is measured in

A

Joule (J)
calorie (cal)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Pressure

A

Pascal (Pa)
millimeters mercury (mm Hg)
atmosphere (atm)
torr, bar, psi

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

kilo (k)

A

1,000

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

centi (c)

A

0.01

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

mili (m)

A

0.001

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

micro (u)

A

0.000001 (5 zeros)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

nano (n)

A

0.000000001 (8 zeros)

22
Q

1 Kilometer =

A

1000 meters (1km = 1000m)

23
Q

1 centimeter =

A

0.01 meters (1cm = 0.01 m)

24
Q

1 millimeter =

A

0.001 meters (1mm = 0.001 m)

25
Q

1 micro meter =

A

0.000001 meters (1um = 0.000001 m)

26
Q

1 nano meter =

A

0.000000001 meters (1nm = 0.000000001 m)

27
Q

Density =

A

mass/volume

28
Q

cathode Ray Tibe Experiment

A

high voltage creates a stream of particles, they bent away from the negatively charged plate and towards the positively charged plate.
conclusion: existence of negatively charged particles (electrons)

29
Q

Rutherords Gold Foil Experiment

A

fired particles at sheet of gold foil, some passed through others bounced back.
conclusion: the mass of the atom is concentrated in the positive nucleus around which electrons move

30
Q

Discovery of neutron

A

James Chadwick

31
Q

Isotopes

A

same element, different number of neutrons, isotopes can be identified by their mass

32
Q

Mass Defect

A

amount of matter converted to energy when the nucleus of an atom is formed from protons + neutrons

33
Q

wavelength (lamda- upside down y)

A

distance between identical points in a wave

34
Q

frequency (v)

A

the number of peaks that pass through a point per unit of time

35
Q

Constructive Interference

A

“in phase” waves come together to become a bigger wave

36
Q

Destructive Interference

A

“out of phase” waves come together to cancel each other out

37
Q

Plum pudding model

A

neutrons + protons –> the dough
electrons –> plum bits scattered throughout

38
Q

Photoelectric effect + equation used

A

shinning light on a metal surface can cause e- to be ejected –> emitted e- are called photoelectrons
can measure photoelectron speed to determine their kinetic energy using =
KE electron = 1/2 (mass or electron)(velocity of electron)^2

39
Q

Light behaves as…

A

A wave and has particle like characteristics

40
Q

the minimum amount of energy required to detach an e- from a surface

A

KE electron = E photon - E0
0 = depends on metals identity

41
Q

Bohr Model

A

only works for H- atom (simplest) not 100% correct, electrons do not orbit nucleus on set tracks

42
Q

Heisenberg Uncertainty Principle

A

we cannot know both the position and speed of a particle, such as a photon or electron, with perfect accuracy; the more we nail down the particle’s position, the less we know about its speed and vice

43
Q

Schrodinger

A

propose mechanical model
–> treats electrons as waves, e- behaves as waves each having a wave function

44
Q

Schrodinger Equation

A

solution to the Schrodinger equation describes the 3D orbital shapes

45
Q

Probability Density function

A

determine the probability of finding the e- in a given region around the nucleus
square of the wave function gives us probability of density

46
Q

atomic orbital

A

region around the nucleus where the e- has 99% probability of being found

47
Q

s orbital

A

3D spherical shape

48
Q

p orbital

A

dumbbell shape

49
Q

d orbital

A

cloverleaf shape

50
Q

Pauli Exclusion Pirinciple

A

no two e- within an atom have the same set of four quantum numbers

51
Q
A