ch. 4-5 Flashcards
3 reasons why carbon is flexible (which allows for diverse molecules)
-carbon bonds: 4 valence electrons, so it can form 4 bonds
-not strongly EN
-bonds are at a max distance at 109.5
carbon often pairs with
H, N, O
isomers
molecules with the same atoms but different arrangement of atoms and electrons
structural isomer
-covalent bonds in dif locations
-molecule is dif shape
geometric isomer
-occurs near a double bond: double bond prevents it from being able to rotate along the axis
trans isomer configuration
-important groups are on OPPOSITE sides of the double bond
-chain is straight
cis isomer configuration
-important groups are on the SAME side of double bond
-chain is bent
enantiomers
differ in spatial arrangement around an asymmetric carbon, resulting in 2 molecules that are mirror images.
most important chemical groups?
hydroxyl, carbonyl, carboxyl, amino, sulfyhdryl, phosphate, methyl
what do functional groups (R Groups) do?
attach to carbon chains and have specific properties; directly involved in reactions
what is a macromolecule
polymer built from a monomer
what is a macromolecule
polymer built from a monomer
macromolecules contain…
billions of pieces which each contain many atoms
two ways of changing polymer length
dehydration reaction and hydrolysis reaction
dehydration reaction
-two molecules are covalently bonded together with the loss of a water molecule
-increases length
polymers are disassembled to monomers by…
hydrolysis
hydrolysis reaction
-bond between monomers is broken by the addition of water
-decreases length
most important macromolecules in all living things:
carbohydrates, lipids, proteins, and nucleic acids
most important macromolecules in all living things:
carbohydrates, lipids, proteins, and nucleic acids
carbohydrates? hydrophilic or hydrophobic?
hydrophilic (dissolve in water)
monosaccaride
sugar monomer
monosaccharide differences: chain lengths can vary
triose: 3 carbons
pentose: 5 carbons
hexose: 6 carbons
monosaccharide differences: placement of carbonyl group
-end of carbon skeleton: aldose
-within carbon skeleton: ketose
monosaccharide differences: placement of carbonyl group
-end of carbon skeleton: aldose
-within carbon skeleton: ketose
monosaccharide isomers ?
same atoms, different arrangements
hydroxyl down
alpha
hydroxyl up
beta
disaccharide
2 monosaccharides joined by a glycosidic linkage
3 main disaccharides
sucrose, lactose, and maltose
sucrose =
glucose + fructose
lactose =
glucose + galactose
maltose =
glucose + glucose
polymers with hundreds of thousands of monosaccharides joined by glycosidic linkages
polysaccharide