C7 - Energy Changes Flashcards
Exothermic
-transfers energy to surroundings
-increase temp of surroundings
-more energy in reactants than in products
Exothermic eg
-combustion
-neutralisation
Endothermic
–take in energy from surroundings
-drop in temp of surroundings
-more energy in products than in reactants
Endothermic eg
thermal decomposition
Hand warmers - disposable
-exothermic
-oxidation of iron
Hand warmers - reusable
-place pack into boiling water to re dissolve crystals
Self heating can
-calcium oxide + water —> calcium hydroxide
-exothermic
Cold packs
-endothermic
-ammonium nitrate + water
-pack is compressed + seal is broken
-reaction occurs
-non reusable
activation energy
minimum energy needed for colliding particles of reactants to have enough energy to cause a reaction
Less energy of particle collisions causes
-bounce off each other
-do not react
Exothermic reaction profile
-high reactants at the start
-low products at the end
Endothermic reaction profiles
-low reactants at the start
-high products at the end
Breaking bonds
-endothermic
-energy is needed to overcome bonds from surroundings
Making bonds
-exothermic
-energy is transferred to surroundings
Exothermic bond energy calculations
-more energy needed to break bonds in reactants
Endothermic bond energy calculations
-more energy needed to form bonds in products
bond energy
energy needed to break the bond between 2 atoms
bond energy units
kJ/mol
overall energy change for exothermic
-negative value
overall energy change for endothermic
- positive value
simple electrical cells
-2 metals dipped in salt solution
-connected by wire
simple electrical cells - electrons
more reactive metal donates electrons to the less reactive metal
the greater the difference in reactivity between the 2 metals
the higher the voltage produced by the cell is
current
flow of electrons
re chargeable batteries process
-battery connected to power supply
-reverses reactions that occurs at each electrode
-regenerates original reactants
hydrogen powered vehicles
hydrogen burns well
pros of h2
-not needed to be electrically recharged
-no pollutants
-range of sizes for range of use
cons of using h2 fuel
-highly flammable
-produced by using fossil fuels
-difficult to store
making hydrogen cons
- via electrolysis
-requires electricity from fossil fuels
-produces co2
-uses finite resources
fuel cells
-oxidises h2
-fed w H2 + O2 to make water
-energy supplies vehicle
-but constant supply of H2 is needed
Reaction at cathode process
-H2 to cathode as fuel
-diffuses through graphite electrodes
-sources electrons to an external circuit
-
Reaction at anode
-o2 to anode
-diffuses through graphite electrodes
-reacts to form OH ions
-accepts ions from external cicuit
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