C3.7 - Giant covalent structures Flashcards
giant covalent structures
huge 3D network of covalently bonded atoms
Properties of giant covalent structures
- insoluble
- very high melting/boiling points
- hard (except graphite)
- cannot conduct electricity (except graphite)
Bonding in graphite
-1 carbon atom is covalently bonded to 3 other C atoms
-forming hexagons - arranged in giant layers
-weak intermolecular forces between layers
+ allowing the layers to slide over each other = soft material
delocalised electrons
electrons that are no longer associate with any particle
-can move around freely
How does graphite conduct electricity
-as only 3 of its electrons are covalently bonded, 1 electron from each atoms is free
-so the delocalised electrons carry electrical charge
+ they move towards the positive terminal in the battery
What happens to graphite when it conducts thermal energy?
- causes the delocalised electrons to move around quicker along the layers of the graphite
- energy is being transferred
Why can diamond not conduct electricity?
- as all 4 of its atoms’ electrons are being used up
- it has no delocalised electrons to carry charge
allotropes
different forms of the same element