3.3 carbohydtrates Flashcards
What are the monomers in volved in making up carboydrates?
monosacharides
What are the two types of glucose molecules and their differneces and similatrities in structure?
Both hexose monosacaride
Alpha - H above the OH group on C1
Beta- OH group above H group on C1
give and example of a
hexose and pentose monosacarides
pentose: eg. ribose 5 carbons
Hexose: eg glucose 6 carbons
what elements make up
carbohydrates?
H O C
Monosacharides join to produce
disacharides or polysacharides
what bond holds monosacharides together
glycosidic (oxygen bridge)
what is the reaction of the synthesis of glycosidc bond called?
condenstation reaction
what reaction breaks the glycosidic bond
hydrolisis
Sugar is a general term for
di or poly sacarides
…………+……….—> maltose
a-glucose+a-glucose
…………+……….—> sucrose
a-glucose + fructose
…………+……….—>lactose
a or b-glucose + galactose
Starch
* function?
* structure?
* properties that make it suited to its function?
* two types and their properties and structure?
Starch
* energy storage in plants (excess glucose)
* made up of** a-glucose**
* insoluble: so wont swell due to osmosis
* - amylose: long, coiled and unbranched for compact sotorage, 1,4 gylcosidic bonds
* -amylopectin:long brancehed chain quick release because enzyme has more acsess points 1,4 glycosidic bonds and 1,6 glycosid bonds
Glycogen
* function?
* structure?
* properties that make it suited to its function?
- energy storage in animals- excess glucose stored as glycogen
- polysacaride of a-glucose 1,4 & 1,6 glycosid bonds
- Very branched more than amylopectin- fast release of glucose for mobile animals
- compact- good for storage
Celluslose
* function?
* structure?
* properties that make it suited to its function?
- cell wall structure and support
- long and unbranched alternating beta glucose with H-bonds between cellulose chains
- strong microfibrils due to the additional H- bonds for further structural support
- beta glucose alternating chain, hydrogen bonds between chains, microfibril, macrofibril, cellulose fibre
B-glucose vs A-glucose chains
Beta- OH group on top so chain is alternating every other monomer is flipped (180) upsidedown relative to neighbouring molecule
Alpha H group on top
which sugars have reducing properties?
maltose and lactose
which sugar has is non-reducing?
sucrose
explain when polymerised glucose forms cellulose and not starch
the hydroxly group on c1 is above the ring so alternate glucose molecules must rotate 180, so the hydroxyfrom c1 and c4 are close enough to react, when condensation takes place this forms glycosidic bonds the rotation of glucose molecules produces straight chain cellulose, the sahpe of alpha molecules that dont need to rotate 180 causes the starch to coil.