Unit 2: carbohydrates Flashcards
when the carbonyl is in the end of a chain
aldo
when carbonyl is in the middle of a chain
keto
different carbon names are based on how many
carbon
carbon name for 2,3.4,5,6,7
di,tri,tetr,pent,hex,sept
anomeric carbon
bond to 2 separate oxygen
monosaccharide functional groups
multiple hydroxyl groups, only one carbonyl group
function of monosaccharide
provide energy and building blocks for other molecules
monosaccharide can form into what shape
rings
alpha and beta structure depends on where _____ is
anomeric hydroxyl group
glucose is
most common and important
fructose
component of table sugar, common energy intermediate
galactose
component of lactose, often found in oligosaccharides
ribose/deoxyribose
pentose sugars used to make DNA/RNA
disaccharides are? what link
two monosaccharides joined together by glycosidic linkage
glycosidic linkage
condensation between two hydroxyl groups, one is always an anomeric carbon
disaccharides primarily for
energy storage
Maltose
glucose + glucose
sucrose
glucose + fructose
lactose
glucose + galactose
polysaccharides
macromolecules, polymers of monosaccharides, 10-100s of subunits long
polysaccharides examples
starch, glycogen, cellulose, chitin
alpha formation
anomeric hydroxyl group below ring
beta formation
anomeric hydroxyl group above ring
storage polysaccharides are made from
alpha-monomers
structural polysaccharides are made from
beta monomers
storage polysaccharides include
complex carbs, starch (planets), glycogen (animals)
.
.
storage polysaccharides features
digestible, helical phone cord structure and store energy
glycogen
storage polysaccharide
1-6 linkages to form branches
branches are good for
releasing energy more at once, not for storage
structural polysaccharides
dietary fiber, cellulose (plants), chitin (insects, crustaceans)
cellulose made from
beta glucose, 1-4 linkages
structural polysaccharides structure
straight linear structure that hydrogen bonds with other strands to form woody fiber
animals do not have enzymes to break down/ digest
beta 1-4 linkages
oligosaccharides
sugars of 3-40 monomers, many different simple sugars,
highly branched
oligosaccharides function
cell recognition/signaling and cell defense
blood types result from
oligosaccharides
amylose
plants
storage alpha 1-4 helical
amylopectin
plants
storage
alpha 1-4 helical
alpha 1-4 branches
glycogen
storage animals
alpha 1-4 helical
alpha 1-4 branches
cellulose
structural plants
beta 1-4 lines (wood)
chitin
structural animals
beta 1-4 lines (exoskeleton)
storage
plants: amylose, amylopectin
animal: glycogen
structural
plants: cellulose
animals: chitin
how to tell beta from a structure
top, two oxygens are close together and they are up
how to tell alpha from a structure
bottom, oxygens are across and one is facing down
monosaccharides 4 main points
- glucose, galactose, fructose, ribose, deoxyribose
- general naming (kato vs aldo; di, tri,tetra, penta, hexa)
- find anomeric carbon
- # a chain
main 2 points of disaccharides
- glycosidic bond used two diff. hydroxyl
2. maltose, sucrose, lactose
main 2 points of oligosaccharides
- highly branched
2. cell recognition and cell defense
main 2&3 points for polysaccharides
storage:
plants –> 1) amylose alpha 1-4 helical. 2) amylopectin: alpha 1-4 helical and alpha 1-6 branched. 3) animal –> glycogen: a1-4 helical and a1-6 branched
structural:
plants –> 1) cellulose: b1-4 lines (wood). animals –> 2) chitin b1-4 lines (exoskeleton)