The Periodic Law Flashcards

1
Q

Dmitri Mendeleev

A

Russian chemist

developed and published the first periodic table of the elements

predicted the discovery of several new elements

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2
Q

Mendeleev’s periodic table

A

organized by increasing atomic mass

showed repeating (periodic) properties in columns

not perfect but highly accurate

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3
Q

Henry Moseley

A

English physicist

discovered that the elements in the periodic table fit into patterns better when they were arranged in increasing order according to the number of protons than by atomic mass

led to the definition of atomic number

rearranged the periodic table by atomic number

discovered the periodic law

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4
Q

periodic law

A

states that the physical and chemical properties of the elements are periodic functions of their atomic numbers

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5
Q

periodic table

A

an arrangement of the elements in order of their atomic numbers so that elements with similar properties fall in the same column

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6
Q

groups

families

A

vertical columns on the periodic table

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7
Q

information given by groups

A

number of valance electrons in elements

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8
Q

quantum numbers given by groups

A

angular momentum quantum number

magnetic quantum number

spin quantum number

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9
Q

range of groups

A

1 to 18

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10
Q

periods

A

horizontal rows on the periodic table

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11
Q

information given by periods

A

number of energy levels in elements

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12
Q

quantum number given by periods

A

principal quantum number

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13
Q

range of periods

A

1 to 7

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14
Q

blocks

A

4 regions of the periodic table containing elements based on the electron configurations of elements

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15
Q

determination of blocks on periodic table

A

sublevel being filled in successive elements of that block

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16
Q

quantum number given by blocks

A

angular momentum quantum number

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17
Q

range of blocks

A

s

p

d

f

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18
Q

s-block

A

group 1 and group 2 on the periodic table

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19
Q

p-block

A

group 13 through group 18 on the periodic table

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20
Q

d-block

A

group 3 through group 12 on the periodic table

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21
Q

f-block

A

lanthanides series and actinide series on the periodic table

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22
Q

main group elements

A

s-block elements and p-block elements

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23
Q

general valence electron configuration of group 1

A

ns1

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24
Q

general valence electron configuration of group 2

A

ns2

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25
general valence electron configuration of group 3
ns2(n-1)d1
26
general valence electron configuration of group 4
ns2(n-1)d2
27
general valence electron configuration of group 5
ns2(n-1)d3
28
general valence electron configuration of group 6
ns1(n-1)d5
29
general valence electron configuration of group 7
ns2(n-1)d5
30
general valence electron configuration of group 8
ns2(n-1)d6
31
general valence electron configuration of group 9
ns2(n-1)d7
32
general valence electron configuration of group 10
ns2(n-1)d8
33
general valence electron configuration of group 11
ns1(n-1)d10
34
general valence electron configuration of group 12
ns2(n-1)d10
35
general valence electron configuration of group 13
ns2np1
36
general valence electron configuration of group 14
ns2np2
37
general valence electron configuration of group 15
ns2np3
38
general valence electron configuration of group 16
ns2np4
39
general valence electron configuration of group 17
ns2np5
40
general valence electron configuration of group 18
ns2np6
41
types of periodicity
atomic radii ionic radii ionization energy electron affinity electronegativity shielding effect chemical reactivity
42
cation
positively charged ions formed by the loss of all valence electrons in an element made from atoms of metals
43
oxidation
loss of electrons
44
anions
negatively charged ions formed by gaining enough electrons to obtain a noble gas configuration made from atoms of nonmetals
45
reduction
gain of electrons
46
atomic radii
distance from the center of the nucleus of an atom to the border of the electron cloud found by calculating half of the distance between the nuclei of identical atoms that are bonded together because there is no definite border of the electron cloud
47
periodic trends of atomic radii
decreases from left to right increases from top to bottom
48
ionic radii
distance from the center of the nucleus of an ion to the border of an electron cloud
49
ionic radii of cations (in comparison to an atom)
smaller than the atomic radius of a neutral atom due to loss of electrons
50
ionic radii of anions (in comparison to an atom)
larger than atomic radius of a neutral atom due to gain of electrons
51
periodic trends of ionic radii
decreases from left to right increases from top to bottom
52
ionization energy (IE)
amount of energy (in kJ/mol) needed to remove 1 electron from a neutral atom
53
nth ionization energy (IEn)
energy (in kJ/mol) needed to remove an atom's nth electron after the (n-1) electrons removed before it
54
periodic trends of ionization energy
increases from left to right decreases from top to bottom
55
electron affinity (EA)
release of energy that occurs when an electron is acquired by a neutral atom
56
periodic trends of electron affinity
increases from left to right decreases from top to bottom
57
reason for electron affinity of last group of each block to be equal to zero
final group of each block has filled all orbitals but new orbitals cannot be built for anions
58
significance of a negative electron affinity value
represents amount of energy released does not represent a negative measurement (not possible)
59
electronegativity
a measure of the ability of an atom in a chemical compound to attract electrons based upon the arbitrarily assigned value of 4.0 to fluorine (most electronegative element)
60
periodic trends of electronegativity
increases from left to right decreases from top to bottom
61
shielding effect
ability of inner electrons to pull on valence electrons
62
periodic trends of shielding effect
constant from left to right increases from top to bottom
63
Jöns Jacob Berzelius
Swedish chemist chose to use Latin to name the elements so that there was a unified name in a language that everybody understood decided to give metals symbols with 2 letters decided to give nonmetals symbols with 1 letter
64
Stanislao Cannizzaro
Italian chemist presented a convincing method for accurately measuring the relative masses of atoms enabled chemists to agree on standard values for atomic mass and other properties of the elements