Arrangement of Electrons in Atoms Flashcards
electromagnetic radiation
a form of energy that exhibits wavelike behavior as it travels through space
electromagnetic spectrum
all the forms of electromagnetic radiation

constant speed of all forms of electromagnetic radiation
3.0 × 108 meters per second
speed of light (c)
3.0 × 108 meters per second
wavelength (λ)
the distance between corresponding points on adjacent waves
units for wavelength
meter
centimeter
nanometer
frequency (v)
the number of waves that pass a given point in a specific time (usually 1 second)
units for frequency
waves per second
hertz (Hz)
Hertz (Hz)
unit of measurement for frequency
equal to 1 wave per second
named for Heinrich Hertz
mathematical relationship between frequency and wavelength
c = λv
wavelength range of visible light
400nm to 700nm
types of electromagnetic radiation (in order of increasing wavelength)
gamma rays
X-rays
ultra-violet
visible light
infrared
microwaves
radio waves
types of electromagnetic radiation (in order of increasing frequency)
radio waves
microwaves
infrared
visible light
ultra-violet light
X-rays
gamma rays
types of electromagnetic radiation (in order of increasing energy)
radio waves
microwaves
infrared
visible light
ultra-violet light
X-rays
gamma rays
quantum
the minimum amount of energy that can be gained or lost by an atom
same thing as a photon
Planck’s constant (h)
6.626 × 10-34 joules by seconds
energy (E)
power that may be translated into motion, overcoming resistance, or causing a physical change
mathematical relationship between a quantum of energy and the frequency of radiation
E = hv
photon
a particle of electromagnetic radiation having 0 mass and carrying a quantum of energy
same thing as a quantum
energy of a photon
Ephoton = hv
ground state
the lowest energy state of an atom
excited state
a state in which an atom has a higher potential energy than it has in its ground state
continuous spectrum
the emission of a continuous range of frequencies of electromagnetic radiation

emission spectrum
the spectrum of light released from excited atoms of an element

absorbtion spectrum
the spectrum of light absorbed from ground-state atoms of an element

Bohr’s model of the hydrogen atom
structural model in which an electron moves around the nucleus only in circular orbits
linked the atom’s electron with photon emission
explained that energy of electron is higher when in orbits that are successively farther from nucleus
quantum theory
describes mathematically the wave properties of electrons and other very small particles
quantum numbers
specify the properties of atomic orbitals and the properties of electrons in orbitals
principal quantum number
indicates distance from nucleus
informal name for principal quantum number
energy levels
identification of principal quantum number
periods on periodic table
symbol of principal quantum number
n
range of principal quantum number
1 to 7
angular momentum quantum number
indicates the shape of the orbital
informal name for angular momentum quantum number
sublevels
symbol of angular momentum quantum number
l
range of angular momentum quantum number
0 to 3
magnetic quantum number
indicates the orientation of an orbital around the nucleus
informal name for magnetic quantum number
orbital
symbol of magnetic quantum number
m
range of magnetic quantum number
-3 to 0 to 3
spin quantum number
indicates relation of electrons on axis
informal name for spin quantum number
spin
symbol of spin quantum number
s
range of spin quantum number
ranges from -0.5 to 0.5
3 basic rules of electron configuration
aufbau principle
Pauli exclusion principle
Hund’s rule
aufbau principle
states that an electron occupies the lowest-energy orbital that can receive it
derived from the German word meaning “building-up”
discovered by Bohr and Pauli

Pauli exclusion principle
states that no 2 electrons in the same atom can have the same set of 4 quantum numbers
Hund’s rule
states that orbitals of equal energy are each occupied by 1 electron before any orbital is occupied by a second electron, and all electrons in singularly occupied orbitals must have the same spin state
3 methods of indicating electron configuration
orbital notation
electron-configuration notation
noble gas notation
orbital notation
a diagramic representation that uses dashes and arrows to show the principal energy levels and sublevels for all the electrons in an atom

electron-configuration notation
method of writing the electron configuration of elements in which coefficients represent the energy level that the electron occupies with the letter of its sublevel and superscripts represent the number of electrons present in an atomic orbital

noble gas notation
an abbreviated version of electron-configuration notation in which filled inner shells are represented by the symbol of the preceding noble gas in brackets
noble gas configuration
an outer main energy level fully occupied (in most cases) by 8 electrons
highest occupied level
electron-containing main energy level with the highest principal quantum number
inner-shell electrons
electrons that are not in the highest occupied energy level