Study Guide 2: Bonding and Structure of Organic Compounds Flashcards
Building blocks of matter
Atoms
contains the protons and the neutron
nucleus
describes an atom and gives the number of protons in the atom’s nucleus
Atomic Number (Z)
composed of the electrons
electron cloud
gives the total number of protons and neutrons
Mass Number (A)
are confined to different regions within the atom
Electrons
are belonging to different layers, or shells, surrounding the nucleus
are belonging to different layers, or shells, surrounding the nucleus
are further grouped into subshells (denoted by s, p, d, f) within each shell, and within each subshell
Electrons
are grouped in pairs into orbitals
Electrons
is a description of the orbitals that the electrons of an atom occupy
Electron Configuration
If two or more degenerate orbitals are available, one electron is placed in each with their spins parallel until all are half-full
Hund’s rule
A maximum of two electrons may be placed in each orbital
but only when the spins of the electrons are paired
Pauli exclusion principle
Orbitals are filled so that those of lowest energy are filled first
Aufbau principle
proposed independently in 1858 that carbon always has four “affinity” units in all organic compounds, i.e., carbon is tetravalent and thus forms four bonds.
August Kekule and Archibald Couper
proposed independently in ________ that carbon always has four “affinity” units
1858
In ________, they proposed that the four bonds of carbon have specific spatial orientation.
1874