Module 2: Polarity, Resonance, and Arrow Pushing Flashcards
Hydrogen must have two ___________ and no _______________________ can have more than ___________________.
electrons
second-row element
eight electrons
Positively charged carbon atoms are called?
carbocations
Two resonance structures must have the same number of?
unpaired electrons
Some molecules can’t be adequately represented by a single Lewis structure
resonance structures
different geometries
- linear
- trigonal planar
- tetrahedral
Hybrid Lewis structures = ?
resonance structures
resonance structures are represented by a?
double-headed arrow
it is the measure of an atom’s attraction for an electron in a bond
electronegativity
it always begins at an electron pair (a bond or lone pair)
tail
The __________________ is more stable than any resonance structure because it delocalizes electron density over a larger volume.
resonance hybrid
it shows where the electrons are coming from
tail
Two Lewis structures having the same placement of atoms but a different arrangements of electrons
resonance structures
These differ in the arrangement of both atoms and electrons
isomers
These are unstable intermediates because they contain a carbon atom that is lacking an octet of electrons
carbocations
Resonance structures must be valid _____________________
Lewis structures
it is the most electronegative
upper right corner
These differ only in the way atoms are connected
constitutional isomers
it shows the movement of an electron pair
curved arrow notation
These are different compounds that have the same molecular formula
isomers
different types of bonds
- single
- double
- triple
It refers to electrons that participates in resonance
Delocalized
It refers to electrons that does not participate in resonance
Localized
A quantity called _______________________ indicates the fraction orbital due to the 2s orbital used to form it.
percent s-character
it shows where the electrons are going
head
different hybridizations
- sp
- sp2
- sp3
As the number of electrons between two nuclei increases, bonds become ________ and ________
shorter, stronger
triple bonds are ________ and _________ than double bonds
shorter, stronger
these differ only in the arrangement of the electrons
resonance structures