Study Guide 1 Flashcards

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1
Q

Define an element and compound. How do the two differ? Explain how the compound NaCl exhibits an emergent property distinct from the elements Na or Cl alone.

A
  • element: a substance that cannot be broken down to other substances by chemical reactions
  • compound: substances consisting of 2 or more elements
  • NaCl exhibits an emergent property distinct from the elements of Na or Cl alone because NaCl is a salt but Na and Cl alone are not salts
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2
Q

List the 4 elements that make up 96% of living matter.

A

Nitrogen, Carbon, Oxygen, Hydrogen

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3
Q

Distinguish between the mass number and the atomic number of an element.

A

the mass number is the sum of the protons and neutrons in an atom; the atomic number is the number of protons

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4
Q

Define an isotope. Are all isotopes radioactive? What happens to the ratio of parent isotope to daughter isotope over a single half-life?

A
  • isotope: atoms of an element that have the same atomic number but different has numbers (different amount of neutrons)
  • not all isotopes are radioactive; the ones that are, decrease by 50% in a single half-life
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5
Q

The half-life of the carbon isotope, 14C, is about 5700 years. Radioactive dating using14C isotopes found in charcoal used in cave painting by early humans in France shows the cave paintings are about 23,000 years old. Approximately, how much 14C isotope remains in the charcoal?

A

approximately 6.25%

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6
Q

How does the distribution of electrons in the valence shell of atoms determine the types of chemical bonds the atom is likely to form?

A

it determines how electronegative the atoms are and if they give up electrons or are likely to take electrons from other atoms to complete its valence shell

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7
Q

Discuss how the valence number coupled with an atom’s electronegativity can be used to predict the type of bonds the atom will form.

A

it determines how electronegative the atoms are and if they give up electrons or are likely to take electrons from other atoms to complete its valence shell

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8
Q

Which of the following types of bonds have the greatest bond energy?

A

covalent bonds

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9
Q

Compare and contrast methane (CH4), oxygen (O2), and water (H2O) in terms of polarity, molecular structure and distribution of electrons.

A
  • CH4: nonpolar, one C bonded to 4 H’s, H are partially positively charged
  • O2: non polar, 2 Os double bonded, O’s are partially negative
  • H2O: polar, one O bonded to two H’s, H’s are partially positively charged, O is partially negatively charged
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10
Q

Compare and contrast sodium chloride to magnesium chloride. What bond holds these salts together?

A

both salts are held together by ionic bonds

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11
Q

List and describe the weak chemical bonds of Van der Waals interactions and hydrophobic interactions. Discuss the important role that the cumulative effect of weak bonds has on biological molecules.

A

Van der Waals and hydrophobic interactions are weak bonds that form in fatty acids; they are non polar and repel water; they are easily broken through changes in pH, temperature and force; however they do allow for structural support such as in the tertiary structure of proteins

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12
Q

12 Carbon has ______ protons, ________ neutrons and ________ electrons. How does 12C differ from 14C?

A

6,6,6; 14C has 6 protons, 8 neutrons, and 6 electrons

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13
Q

How many electrons does carbon need to fill its outer valence shell?

A

4

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14
Q

Draw the Lewis structure (dot diagram) of Carbon.

A

:C:

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15
Q

How many covalent bonds can carbon form with other elements?

A

4

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16
Q

Hydrogen has ______ protons, ________ neutrons and ________ electrons.

A

1, 0, 1

17
Q

How many electrons does hydrogen need to fill its outer valence shell?

A

7

18
Q

Draw the Lewis structure (dot diagram) of H2

A

H:H

19
Q

The image shows 5 molecules of liquid water. State the total number of covalent bonds shown in the image.

A

10

20
Q

Explain why the center water molecule can form 4 hydrogen bonds.

A

the oxygen in the center water molecules has two spots left for bonding

21
Q

Define and distinguish between a calorie, a kilocalorie and a joule

A
  • Calorie: the amount of heat that 1 g of water releases when it cools to 1 degree C
  • kilocalorie: 1000 Calories, amount of heat required to raise the temp of 1 kg of water to 1 degree C
  • Joule: (.0239 cal)
22
Q

Explain why the thermal energy of a large body of water located in northern latitudes can be greaterthan the thermal energy of a boiling pot of ramen noodles.

A

thermal energy is not equal to temperature

23
Q

How many calories are consumed if you drink one liter of room temperature water?

A

0

24
Q

How many calories does it take to heat one liter of water by one degree Celsius? (1 gram of water is equal to 0.001 liter)

A

1000 Calories or 1 kg

25
Q

water’s high specific heat

A

caused by hydrogen bonds bc the heat energy must break the bonds before it is able to raise the temp of water

26
Q

water’s cohesive properties

A

hydrogen bonds hold the substance together and allow transport of water and dissolved nutrients

27
Q

water’s adhesive properties

A

hydrogen bonds allow water to cling to another substance

28
Q

water’s solvent properties

A

hydrogen bonds allow water to be a solvent

29
Q

Solution, solvent, solute, hydration shell, aqueous, hydrophilic, hydrophobic, amphipathic, pH, hydroxide ion, hydronium ion, acid, base, buffer systems

A
  • solution: a mixture of 2 or more substances that is completely homogenous
  • solvent: dissolving agent of a solution
  • solute: substance that is dissolved
  • hydration shell: sphere of water molecules around each dissolved ion
  • aqueous: relating to water
  • hydrophilic: attracted to water
  • hydrophobic: repels water
  • amphipathic: hydrophobic and hydrophilic
  • pH:negative logarithm of H+ concentration
  • hydroxide ion: (OH-) the water molecule that lost its H+
  • hydronium ion: (H3O+) proton bonds to another water molecule
  • acid: a substance that increases the H+ ion concentration of a solution
  • base: a substance that reduces the hydrogen ion concentration of a solution
  • buffer systems: a substance that minimizes changes in the concentration of H+ and OH- in a solution
30
Q

define the molecular mass.

A

sum of masses of all atoms in a molecule