Porcelain Flashcards
What is in kaolin?
Al2o3. 2sio2. 2H2O
Hydrated aluminosilicate
What are the components of porcelain?
Kaolinite
Quartz
Feldspar
What is quartz made from?
SiO2
What is the most common element in the earth?
Silica
What is feldspar?
Mixture of potassium and sodium aluminosilicates
K20 Al2O3 6SiO2
N20
What are dental porcelains mainly composed of?
mainly Felspar some quart hardly any qaolin
What is the differnce in compostition of high fusing and low fusin porcelain?
percetntage: Kaolin, Silica, Feldpar, Glasses
High fusing: 4, 15, 80, 0
Low fusing:, 25, 60, 15
Metal oxides less than 10%
Wen are high fuse porcelains used?
they are used mainly for PJC
they fuse at around 2400 degress
When are low fuse porcelains used?
these are used to provide the glaze
What are the other componenents added to porcelain?
Borax: sodium borate
Metal oxides
What is the purpse of adding sodium borate, and to what component is it added to?
this is added to feldspar
added to reduce melting temp
What are the two types of metal oxides added for?
pigments and opalscence
Which metal oxides are added for pigmentation?
iron: brown
copper: green
coablt: blue
Which metal oxides are added for opalscence *transparity?
Zno
Titanium oxide
What are the physical properties of porcelain?
Low thermal conductivity: good since does conduct heat to pulp, bad since thermal stresses can lead to fracture
Excellent aesthetcs
wide range of shades so can mimic dentine and enamel
What determines the opacity or trasparency of porcelains composte and ceramic materials?
partcle size and index of refraction of the differnt components
WHat was the issue with having kaolin in porcelain?
it was initally added to increase the abilty to mould and shape the porcelain however, since it was opaque it made it difficlt to achieve a high transluceny of porcelain
What are the chemical and biological properties of porcelain?
bicompatoble
stable
need to ensure that porcelain is glazed since only polishing makes the surface quite rough and promotes plaque accumulation
t/f porcelain is harder than enamel?
t
vickers hardness is 450 vs 350 for enamel
What are the mechanical properties of procelain?
brittle
lacks fracture toughness
fails via catostrophic failure and static fatigue
What are is static fatigue?
decrease in strength over time even in the abscence of load but is accelrated by dynamic loading
SiO bonds slowly hydrolysed and this genreats a rise in OH which elevates pH. this then dissolves oout the Na2O and the K2O (feldpsathic components)
WHat is catostrphoc failure?
this is when the porcelain actually chips away and due to its brittle nature and is rapid.
How is the stength of the porcelain reduced?
surface roughness
internal voids
porosity
How can the mechaical properties of porcelains be improved?
- Alter processing: optimising the fabrication condition
- produce stronger procelains: optimising the compostions and microstructure
- Reinforce porcelain by providing a solid core : structure optimisation
What are the 5 processing imprvments?
Careful tooth prep: redices stresses inside the crown
Use finer grain powder: gives a more unifrom microstructure and surface
Fire at vacuum or under pressure: reduces porosity
Cool slowly from furncae: reudces thermal stresses which can cause cracks
Smooth or further fusing: reduces surface roughness and imprefections
WHat are the three ways of priducing stronger porcelains?
most common method of failure is via crack propagation from the surface irregularties so need a compressive strenght to combat the froces created at surface imperfections
- Ion exchange: xreates compressive forces all over surface by soacking the fired porcelain in molten potassium salt
- thermal stengthening: careful applicaton of heat during inital firing or later heat tempering.
- adding strengthening particles:alumina added will act as crack stoppers. plate like mica or needle like crystals eg lithium disiclicate are added