Polymers Flashcards

1
Q

What are the 3 corner stones of polymer science

A

colloids and interfaces

organic chemistry

physical chemistry

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2
Q

what role do polymers have in pharmacy

A

drug delivery
devices
packaging
active ingredients

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3
Q

how are polymers used in drug delivery

A
tableting
solubilisers
emulsifiers
gels
coatings
pharmacologically active polymers
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4
Q

how are polymers used in devices

A

inahlers

injectors

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5
Q

what is the difference between polymers and small molecules

A

aggregate state
dissolution
solution properties
mechanical properties

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6
Q

What state can polymers never be in

A

gaseous state

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7
Q

what is the first state of polymer dissolution

A

swelling

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8
Q

Polymer solutions vs solutions viscosity

A

have higher viscosity compared to solutions of low molecular weight substances of the same concentration

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9
Q

can polymers show elasticity and reversible deformations

A

yes under certain conditions

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10
Q

what is a monomer

A

monomer, a molecule of any of a class of compounds, mostly organic, that can react with other molecules to form very large molecules, or polymers.

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11
Q

what is an oligomer

A

a polymer whose molecules consist of relatively few repeating units.

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12
Q

what is a polymer

A

polymer, any of a class of natural or synthetic substances composed of very large molecules, called macromolecules, that are multiples of simpler chemical units called monomers.

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13
Q

what is a macro molecule

A

is a molecule that consists of one or more types of repeated ‘building blocks’.

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14
Q

what is a polymer chain

A

Polymer chains are fractal objects whose dimensionality is determined by interactions between the monomeric units and solvent molecules.

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15
Q

what is an elementary unit

A

One of the individuals which, in the aggregate, compose a population: the smallest unit yielding information which, by suitable aggregation, leads to the population under investigation.

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16
Q

What is degree of polymerisation

A

The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule

17
Q

What is polydispersity

A

polydispersity is defined as the weight average divided by the number average molecular weight (Mw/Mn)

18
Q

What is homopolymers and copolymers

A

A homopolymer is a polymer where every monomer unit (mer) of the chain is the same

a polymer made by reaction of two different monomers, with units of more than one kind.

19
Q

how do we calculate the molecular weight of a polymer

A

take weight of repeating unit then multiply by the degree of polymerisation

20
Q

what is configuration (molecular architecture)`

A

refers to the order that is determined by chemical bonds. The configuration of a polymer cannot be altered unless chemical bonds are broken and reformed.

21
Q

What is it called when only one type of monomer is used to build a macromolecule

A

homopolymer

22
Q

what are the 6 types of molecular architecture of homopolymers

A
branched
linear
ladder
star
dendrimer
crosslinked
23
Q

what are the four types of copolymers

A

statistical random copolymers
alternating copolymers
block copolymers
graft copolymers

24
Q

What are the two main types of polymers

A

natural

synthetic