Oligosaccharides & Polysaccharides Flashcards

1
Q

Define oligosaccharides.

A

A condensation product of 3-10 monosaccharides

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2
Q

True or False:

Most oligosaccharides are not digested by human enzymes

A

True

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3
Q

What is another name for raffinose? What is it?

A

Melitose

Trisaccharide

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4
Q

Define polysaccharide

A

high molecular weight polymers

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5
Q

Most carbs found in nature occur as

A

polysaccharides

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6
Q

Polysaccharides are

A

large molecules of monosaccharides that are connected to each other through their anomeric carbons

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7
Q
  1. Polysaccharides are condensation products of _____

2. They can be ______ or _____

A

more than 10 monosaccharide units

linear or branched

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8
Q

3 biologically important polysaccharides are:

A

starch, glycogen, and cellulose

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9
Q

All 3 (biologically important polysaccharides) are ________ but they differ in the type of ______ ______ and/or the amount of ________

A

polymers of D-glucose
glycosidic bond
branching

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10
Q

How do polysaccharides differ from each other?

A
  • identity of their monosaccharide units
  • length of their chains
  • types of bonds linking the units
  • degree of branching
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11
Q

What are polysaccharides classified into?

A

homopolysaccharides

heteropolysaccharides

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12
Q

Homopolysaccharides

A

when polysaccharides are composed of a single type of monosaccharide building block

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13
Q

Heteropolysaccharides

A

polysaccharides composed of more than 1 type of monosaccharide

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14
Q

Examples of Homopolysaccharides

A

starch
glycogen
cellulose
dextrins

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15
Q

Heteropolysaccharides can be divided into

A

glycoseaminoglycans and mucilages

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16
Q

Examples of glycoseaminoglycans

A

hyluronic acid
heparin
ABO blood

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17
Q

Examples of Mucilages

A
  • agar
  • pectins
  • hemicellulose
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18
Q

Starches and dextrins ( polysaccharides)

A
  • digested by human enzymes

- its hydrolysis provide glucose (the most important carb)

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19
Q

Nonstarches (polysaccharides)

A

not digested by human enzymes and are the major component of dietary fiber

20
Q

What are the 2 types of polysaccharides?

A

storage polysaccharides

structural polysaccharides

21
Q

Storage and structural polysaccharides are made up of _______ _____, but they are _________ and ________ different

A

glucose units

structurally and functionally

22
Q

Storage polysaccharides

Name 3

A

contain only a-glucose units

3 important ones are starch, glycogen, and amylopectin

23
Q

Structural polysaccharides

Name 2

A

contain only B-glucose units

2 important ones are cellulose and chitin

24
Q

Chitin contains a

A

modified B-glucose unit

25
Function of Starch
the main storage form of glucose in plant cells
26
Structure of Starch
its structure is identical to glycogen except for a much lower degree of branching (ab every 20-30 residues)
27
Pure starch is ............ Powder that is ......... Found in ........... Gives blue color with ...........
white, tasteless, and odorless insoluble in cold water wheat, rice, corn, potatoes iodine
28
What is amylose?
a glucose polymer with a(1-->4) linkages
29
What is amylopectin?
a glucose polymer with mainly a(1-->4) linkages, but it also has branches formed by a(1-->6)
30
Function and Location of Glycogen
- a storage polysaccharide found in animals | - stored in the liver and muscles
31
Structure of Glycogen
its structure is identical to amylopectin, except that a(1-->6) branching occurs about every 12 glucose units
32
When glucose is needed, glycogen is
hydrolyzed in the liver to glucose
33
Function of Cellulose
the main constituent of the plant's cell wall
34
Cellulose is
insoluble
35
Structure of Cellulose
a polysaccharide consisting of a linear chain of several hundred to over 10 thousand B (1-->4) linked B-D-glucose units
36
Why can some animals digest cellulose? Which animals?
some animals can digest cellulose with the help of bacteria in their stomachs -ruminants and termites
37
How do human digest cellulose?
we do NOT have the enzymes needed to digest the bonds in fibers
38
What can cellulose be called? | What does it act as?
dietary fiber | acts as a hydrophilic bulking agent for feces
39
What inulin? | Where is it found?
- It's a polysaccharide of fructose | - its found in tubers and roots of some plants, readily soluble in water
40
What can inulin be used for?
determining the glomerular filtration rate
41
Can inulin be hydrolyzed by intestinal enzymes?
no
42
What are the fructose units in inulin joined by?
a B (2-->1) glycosidic bond
43
In general, plant inulin polymers contain between
20 and several thousand fructose units
44
What is chitin? | What is composed of?
- is a structural polysaccharide found in the exoskeleton of insects - composed of N-acetylglucoseamine units linked by B1-->4 bond
45
What is dextrin?
the intermediate in the hydrolysis of starch