Energy Changes- Paper 1 Flashcards

1
Q

What is there always changes in whenever chemical reactions occur?

A

Energy

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2
Q

Is energy created, moved around or destroyed in chemical reactions?

A

Moved around

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3
Q

What is an exothermic reaction?

A

A reaction which transfers energy to the surroundings usually by heating-shown by a rise in temp

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4
Q

Give an example of an exothermic reaction.

A

Burning fuels (combustion) which gives out a lot of energy. Or a neutralisation (acid+alkali) reaction.

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5
Q

Are oxidisation reactions usually endothermic or exothermic?

A

Exothermic e.g. adding sodium to water releases energy.

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6
Q

Give everyday examples of exothermic reactions.

A

Self heating cans of hot drink rely on exothermic reactions between chemicals in their bases.

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7
Q

What is an endothermic reaction?

A

A reaction that takes in energy from the surroundings- shown by fall in temperature.

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8
Q

Which are more common, exothermic or endothermic reactions?

A

Exothermic reactions.

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9
Q

Example of endothermic reaction?

A

Citric acid and sodium hydrogencarbonate

Thermal decomposition e.g. heating calcium carbonate causes it to decompose into calcium oxide and carbon dioxide.

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10
Q

Give some everyday examples of endothermic reactions

A

Sports injury packs- chemical reaction allows the pack to become instantly cooler without having to put it in the freezer.

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11
Q

What equipment would you need to measure the amount of energy released by a chemical reaction?

A

Polystyrene cup, lid, thermometer, large beaker, cotton wool and the reaction mixture.

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12
Q

Method for practical?

A
  1. ) Put 25cm3 of 0.25mol/dm3 of hydrochloric acid and sodium hydroxide in seprate beakers.
  2. ) Place the beakers in a water bath set to 25 degrees until they are both at the same temp.
  3. )Add HCl followed by the NaOH to a polystyrene cup with a lid.
  4. ) Take the temp of the mixture every 30 seconds and record the highest temp.
  5. ) Repeat using 0.5 and 1mol/dcm3 of hydrochloric acid
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13
Q

What does an exothermic reaction profile look like?

A

The curve will start mid graph, then curve up and then down far past the reactants point. That shows how much energy was released.

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14
Q

What does an endothermic reaction profile look like?

A

The curve starts at the bottom (reactants) and curves up and then when it falls it stops mid way. This shows the energy absorbed.

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15
Q

On a graph where does the activation energy measure?

A

From the reactants to the highest point of the curve.

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16
Q

How does the graph show it’s endothermic?

A

Because the products are at a HIGHER energy than the reactants.

17
Q

How does the graph show it’s exothermic?

A

Because the products are at a LOWER energy than the reactants.

18
Q

What is an electrolyte?

A

A solution that can conduct electricity, e.g. a solution of an ionic compound.

19
Q

What is true about cells and how long they last?

A

They can only produce electricity for a certain period of time. Eventually the chemicals in the cells run out.

20
Q

When do cells produce electricity?

A

If we use metals with different reactivities.

21
Q

The size of the potential difference depends on….

A

the difference in reactivity between the metals.

also the electrolyte

22
Q

What is a battery?

A

A battery contains two or more cells connected in series to produce a greater voltage

23
Q

What is a non-rechargeable battery?

A

An alkaline battery as once the reactants run out no more electricity can be produced and there is no way to reverse this reaction.

24
Q

What is a rechargeable battery?

A

Rechargeable batteries can be recharged as we can reverse the chemical reactions we applying an electrical current.

25
Q

What do you react in a hydrogen cell?

A

hydrogen and air or pure oxygen.

26
Q

What is the only waste product of a hydrogen fuel cell?

A

Water

27
Q

What is the equation at the negative electrode?

A

2h2—> 4h+ +4e-

28
Q

What is happening to the hydrogen in the fuel cell?

A

It is becoming oxidised

29
Q

List the disadvantages of Rechargeable batteries

A

They become less efficient as they store less electricity the more charging cycles they go through and need replacing eventually.

They require recharging once they’ve run out

30
Q

List advantages of hydrogen fuel cells

A

Can be a source of drinking water e.g. on spacecraft

Don’t get less efficient the longer they run

Produce electricity for as long as you are providing hydrogen for them

31
Q

List advantages of rechargeable batteries

A

No dangerous fuels are required.

Produce a greater pd than a hydrogen fuel cell.

32
Q

List disadvantages of hydrogen fuel cells

A

Hydrogen is an explosive gas so difficult to store safely.

Produce a low pd so several are need together.

33
Q

Energy is….. when new bonds are formed

A

Energy is released when new bonds are formed.

34
Q

Bond formation is

A

Exothermic

35
Q

Bond breaking

A

Endothermic

36
Q

Energy must be …… to break existing bonds

A

Supplied.

37
Q

What are the 3 steps to calculating bond energy?

A

Find the energy required to break the bonds

Find energy released from the forming of new bonds

Find the overall energy change (CAN BE NEGATIVE)

38
Q

What IS activation energy?

A

Minimum amount of energy the reactants need to collide with each other and react.