Chemical Safety, Copper Reactions, Freezing Point Depression Flashcards

(98 cards)

1
Q

refers to the protection of people and the environment from chemical hazards

A

chemical safety

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2
Q

is a type of occupational hazard that is caused by exposure to various chemicals in the workplace and other places where they are used as school laboratory and even at home

A

chemical hazard

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3
Q

is the international standard agreed upon by various countries under the auspices of the United Nations in defining and classifying chemical hazards and communicating these hazards

A

globally harmonized system of classification of labeling of chemicals

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4
Q

enforces the GHS

A

occupational health and safety (OHS)

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5
Q

in the Philippines, is the enforcing agency under the Department of Labor and Employment (DOLE)

A

Occupational Safety and Health Center (OSHC)

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6
Q

chemical hazards are classified into three main hazard groups namely

A

physical
health
environmental

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7
Q

refer to chemical agents that can cause harm with or without contact

A

physical hazards

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8
Q

physical hazards can be (8)

A

explosive substances
flammable liquids
flammable solids
flammable gases
oxidizing substances
toxic and infectious substances
corrosive substances
misc. dangerous susbtances to the environment

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9
Q

refer to chemical agents that can deleteriously affect one’s health

A

health hazards

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10
Q

health hazards can be (6)

A

acutely toxic chemicals
chemical irritants and sensitizers
mutagenic substances
carcinogenic substances
reproductive toxicants
chemical with specific target organ of toxicity (STOT)

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11
Q

refer to chemicals that are particularly toxic to aquatic organisms on short-term or long-term exposure

A

environmental hazards

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12
Q

made up of a red diamond in a white background with the universally-established symbol for nine general chemical hazards

A

chemical hazard symbol or pictogram

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13
Q

physical hazard in detonating bomb

A

explosion hazard

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14
Q

physical hazard in gas cylinder

A

gas under pressure

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15
Q

physical hazard in test tube with a chemical that corrodes a metal or skin on the human hand

A

corrosion hazard

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16
Q

physical hazard in flame over circle

A

oxidizers

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17
Q

meaning of skull and cross bone

A

acutely toxic and poisonous substance

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18
Q

meaning of suffocating head

A

general head hazard

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19
Q

used for less acutely toxic chemicals which is also a health hazard

A

exclamation point

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20
Q

symbol used for environmental hazard

A

dying fish and tree

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21
Q

identify the GHS hazard symbol/pictogram

A

grade yourself accordingly

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22
Q

process of conveying chemical hazards through chemical labeling and safety data sheets

A

hazard communication

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23
Q

it is the name of the chemical product. The UN number pertains to four-digit United Nations product identifier number for hazardous material in the framework of international transport

A

product identifier

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24
Q

which is the internationally-accepted unique numerical identifier assigned to all known chemical substances described in its open scientific literature

A

chemical abstract service number

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25
it is the hazard level associated with a chemical where “danger” signifies the most severe hazard while “warning” signifies a less severe one
signal word
26
these are phrases that describe the hazardous nature and degree of the product that is reflected on the chemical’s SDS
hazard statement
27
these are phrases that describe the general precautions in the use, storage, and/or disposal of a chemical which is also reflected in its SDS
precautionary statement
28
it gives the name, address, and contact details of the chemical supplier/manufacturer of the chemical product
supplier identification
29
these are the universal chemical hazard symbols associated with a chemical as per GHS standard
hazard symbols/pictogram
30
a technical sheet that gives a concise yet comprehensive safety information on chemical product or its mixtures
safety data sheet
31
has a total of 16 sections
GHS-compliant SDS
32
require the availability of SDS for all chemical used in the workplace including academic laboratories
Occupational Safety and Health (OSH) standards
33
used as a household toilet cleaner is concentrated hydrochloric acid (HCl) although in laboratory grade
muriatic acid
34
when used with HCl generates toxic chlorine gas
bleach
35
equipment worn to minimize exposure to any workplace hazard, when working with chemicals
personal protective equipment (PPE)
36
example of PPE
laboratory gown goggles gloves closed shoes face mask
37
proper ventilation and laboratory safety equipment are essential when working with chemicals
engineering controls
38
standard features in a chemical laboratory to prevent its contamination with chemical fumes
fume hood and exhaust fans
39
include metals, minerals and non-metals
inorganic chemicals
40
carbon-containing chemicals
organic chemicals
41
based on these, each chemical group was subdivided into compatible chemical family
reactivity
42
within this, the various chemicals may then be arranged alphabetically for easier identification and self-designed systematic codes may also be incorporated for more efficient inventory purpose
compatible family
43
some chemicals require specific storage
corrosive and flammable chemicals
44
inorganic acids and some organic acids that are best kept in a corrosive/acid cabinet which is made up of wood with acid-resistant epoxy coating or dense plastic material
corrosive chemicals
45
never store corrosive chemicals in these as it is prone to corrosion by the acids
metal cabinets
46
examples include alcohol, ethers, ketones, and hydrocarbons
flammable chemicals
47
material of cabinets where flammable chemicals can be stored,
dense steel
48
used to evaluate a chemical reactio
balanced chemical equation
49
Shows the reactants and products
balanced chemical equation
50
Gives the number of moles of each substances used and produced
balanced chemical equation
51
the maximum amount of the product formed from a given amount of the reactants based on the balanced chemical equation
theoretical yield
52
the amount of product that is finally obtained after carrying out a reaction
actual yield
53
computed with the ratio of the actual yield to the theoretical yield multiplied by 100
percent yield
54
percent yield formula
actual yield / theoretical yield x 100
55
reaction that allowed for the recovery of copper whose mass will be determined to calculate for the % yield
CuSO4 (aq) + Zn (s) -> Cu (S) + ZnSO4 (aq) Cupric sulfate + Zinc -> Copper + Zinc sulfate
56
observation with the addition of HNO3 to copper wire
solution dissolved the copper metal, the color changed into green and produced red fumes
57
observation in addition of distilled water to the reaction mixture
the diluted solution turns into a light blue hue
58
addition of NaOH to the solution
light blue solution turns into a deep blue solution
59
heating the reaction mixture
deep blue solution turns into a black color
60
addition of H2SO4 to the black precipitate
the solution cleared up and turned into blue
61
addition of Zn to reaction mixture
black precipitate dispersed into red solids and likewise dissolved
62
is the temperature at which the liquid and solid phase of the substance exist in equilibrium with each other
freezing point
63
one can determine the freezing point by plotting this
cooling curve
64
solution containing these can lower the freezing point of the solution compared with that of a pure solvent
nonvolatile solute
65
colligative property of a solution that is dependent on the amount of the solute and not on the nature of the solute particles
freezing point depression
66
symbol for freezing point depression
𝛥𝑇𝑓
67
other colligative properties include
boiling point elevation vapor pressure lowering osmotic pressure
68
formula for freezing point depression
𝛥𝑇𝑓 = Kfm
69
Kf means
molal freezing point depression constant that is dependent on the solvent
70
m means
molality of the solution
71
molality of the solution formula
moles of solution / mass in kg solvent
72
technique that is used to experiment and acquire information about a solution containing an acid or base
acid-base titration
73
an analytical chemistry technique used to find an unknown concentration of an analyte (the titrand) by reacting it with a known volume and concentration of a standard solution (titrant)
acid-base titration
74
analyte
titrand
75
standard solution
titrant
76
typically used for acid-base reactions and redox reactions, help determine their acidic or basic properties
titrations
77
decides the endpoint in Titration
indicator
78
used to calculate the amount of a known acidic or basic substance through acid-base reactions
acid-base titration
79
latin word where Titration come from which means an inscription or title
titulus
80
implies the determination of the concentration or rank of a solution with respect to water with a pH of 7
titration
81
added from an apparatus known as the burette
standard solution
82
the process of adding a standard solution until the reaction is complete
titration
83
specific conditions that reactions can be considered as titrations
Reaction has to be fast Change in free energy during the reaction must be large enough for the spontaneity of the reaction There must be always a way to decide the completion of the reaction
84
stage that shows the completion of reaction
endpoint
85
Detected by a physical change that is produced by the solution itself or by the addition of a reagent known as an indicator
endpoint
86
stage where the amount of reagent added is exactly equivalent to the amount of reacting substance in the titrated solution
equivalent point
87
At the equivalence point in an acid-base titration (neutralization), the moles of the acid are what to the moles of the base
equal
88
show the relation between the moles of the acid and volume of the acid to the moles of the base to the volume of the base
MacidVacid = MbaseVbase
89
typically detected only after the addition of a slight excess amount of titrant
endpoint
90
amounts to an error to the experiment
difference between endpoint and equivalent point
91
is when a solution of unknown strength adds to a specific volume of a treated sample containing an indicator
titration
92
the main active ingredient in vinegar, a common household product that is used for cooking and even for cleaning
acetic acid
93
percentage of acetic acid in commercially available vinegar
4-7 percent
94
used as a titrant to react with the acetic acid in vinegar based on the reaction:
NaOH
95
reaction between acetic acid and sodium hydroxide
HC2H3O2 + NaOH -> NaC2H3O2 + H2O
96
type of reaction which takes place in the presences of phenolphthalein
neutralization
97
completion of reaction can be monitored by the change in color of the phenolphthalein
light pink
98
m/v percent formula
g of mass / vol of solution x 100