Alkane Reactions Flashcards
hydrocarbons wherein all bonds around carbon atom are single bonds, that is, all the carbon are sp3 hybridized
alkane
all the bonds are sigma bonds, the geometry is tetrahedral, and the angle between the bonds is 109.5o
what type of hybridized carbons
Sp3
general formula for alkane, where n is any integer
CnH2n+2
ethane number of C and H atoms
C- 2
H - 6
alkanes are these thus the intermolecular force of attraction amongst the molecules is wander vaals and therefore the melting point and boiling point are relatively lower than other organic compounds of the same number of carbon atoms
nonpolar
The number of carbons ____ both the melting point and boiling point
increase
The increase of the length of the carbon chain _____ the surface area of molecules
increases
as the branching increases the melting point and the boiling point ____
decreases
most important sources of alkane
gas and petroleum
process to obtain alkanes from natural sources
distillation
set a systematic way of naming organic compounds (IUPAC)
Union of Pure and Applied Chemistry
set a systematic way of naming organic compounds (IUPAC)
Union of Pure and Applied Chemistry
identify the special branched constituents
grade yourself accordingly
reaction of alkane with molecular oxygen, O2. In the presence of heat to produce carbon dioxide, CO2, and water, H2O. The general equation is written as:
combustion
what will the alkane react with in a combustion reaction
oxygen
product of combustion reaction
CO2 + H2O
draw the products of alkanes in combustion reaction
grade yourself accordingly
three possible reactions of alkanes
combustion
cracking
halogenation
involves the breakdown of long chain alkanes to smaller chain alkanes with the use of high temperature or catalysts
cracking
two types of cracking
thermal cracking
catalytic cracking
carried out at a temperature of approximately 750oC and at a pressure of 70 atm
thermal cracking
temperature and pressure of alkane cracking
750 degrees
70 atm
Gives a mixture of products with a high proportion of hydrocarbons with carbon to carbon double bonds (alkenes)
thermal cracking
uses a zeolite catalyst that allows cracking to take place at a lower temperature (500oC) and pressure
catalytic cracking