Alkyne Reactions Flashcards

1
Q

unsaturated hydrocarbons that contain a -C ΞC- and such that one sp hybridized carbon atom

A

alykne

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2
Q

has linear geometry

A

alkyne

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3
Q

similar to alkenes, thesealso contain pi electrons that are capable of undergoing electrophilic addition reaction

A

alkyne

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4
Q

happens in the presence of hydrogen gas and metal catalyst also produces alkyne just like in alkene

A

hydrogenation

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5
Q

catalyst in hydrogenation in alkynes

A

Lindlar’s Catalyst (Pd in CaCO3 and quinoline)
Na in NH3

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6
Q

addition of to an alkyne follows Markovnikov’s rule and one may use one or two moles of the reagent

A

HX and X2

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7
Q

reactions in alkyne

A

hydrogenation
halohydrogenation
halogenation
hydration
oxidation

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8
Q

requires the presence of mercuric sulfate and forms a ketone instead of an alcohol

A

hydration

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9
Q

the number of carbon chain in an alkyne can be increased by reaction of a terminal alkyne with a very strong base followed by reaction with alkyl halide (RX).

A

formation of acetylide ion

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10
Q

– have an acidic proton and therefore reacts with metal or very strong base

A

terminal alkyne

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11
Q

the products formed in the oxidation of alkyne depends on the type of alkyne; internal or terminal alkyne

A

oxidation reaction

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