Alkene Reactions Flashcards

1
Q

generally classified as unsaturated hydrocarbon because the presence of multiple bonds

A

alkene and alkyne

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

organic compound that must have at least one sp2 hybridization carbon atom or -C=C.

A

alkene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

geometry of alkene

A

planar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

geomtery of alkyne

A

linear

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

angle of bonds of alkene

A

120 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

angle of bonds of alkyne

A

180

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

simplest alkene

A

ethene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

simplest alkyne

A

ethyne

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

must have at least one sp hybridized carbon atom or -C≡C-

A

alkyne

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

has a suffixes modified to -ene

A

alkene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

named using the IUPAC system using -yne

A

alkyne

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

name the alkyne and alkene

A

grade yourself accordingly

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

For compounds containing both a double bond and a triple bond, priority is given to the what

A

alkyne

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

suffix of compounds containing both a double and trible bond

A

-enyne

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

However, if the double bond and the triple bond will have the same position in the numbering the carbon chain, then priority is given to the

A

double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

The double bond will receive the ___ in terms of position

A

lower number

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

C=C- makes alkene relatively more reactive than alkane

A

presence of pi electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

can undergo electrophilic addition reaction with the general mechanism shown below

A

alkene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

involves the breaking of pi bonds to form two new single bonds

A

electrophilic addition reaction

20
Q

Reaction involves an electrophile which is an electron pair acceptor

A

electrophilic reaction

21
Q

intermediate formed in a electrophilic addition reaction

A

carbocation

22
Q

can be primary, secondary, tertiary, formed during electrophilic addition reaction

A

carbocation

23
Q

determine the type of carbocation in ppt

A

grade yourself accordingly

24
Q

most stable followed by secondary and the least is primary carbocation

A

tertiary carbocation

25
one carbocation is formed, this attacks the carbocation to form the product as shown in the mechanism
nucleophile
26
types of alkene reaction
Halogenation Hydrogenation Hydrohalogenation Halohydrin formation Acid catalyzed hydration Oxidation Hydration
27
determine the type of alkene reaction
grade yourself accordingly
28
this reaction follows anti-Markovnikov’s Rule because it follows free radical mechanism instead of a carbocation intermediate
addition of HBr in the presence of peroxide
29
the addition of -H to the -C=C follows this rule
Markovnikov's rule
30
states that “hydrogen is added to the carbon with the most hydrogens and halide is added to the carbon with the least hydrogens”, this will form a more stable carbocation
Markovnikov's rule
31
still follows Markonivkov’s rule and is acid catalyzed
hydration of alkenes
32
rearrangement is possible via this to form a more stable carbocation
hydride shift
33
follows anti-addition and forms vicinal dihalide
Halogenation
34
halogens that can be added to alkene
Cl or Br
35
addition of halogen in the presence of water
halohydrin formation
36
Follows Markovnikov’s rule wherein the halogen adds to the carbon with the most number of hydrogen atoms
halohydrin formation
37
alkenes transformed to alkanes by addition of hydrogen gas in the presence of a metal catalyst
hydrogenation
38
Most common metal catalyst are:
nickel platinum palladium
39
oxidation of alkene via this process forms aldehyde and ketone
ozonolysis
40
breaks the double bond in ozonolysis
oxidative cleavage
41
Considered a weak oxidation of alkene
ozonolysis
42
common reducing agents
Zinc (Zn) dimethyl sulfide (CH3)2S)
43
stronger oxidizing agent and in acidic medium results in formation of carboxylic acid and ketone
KMnO4
44
produces CO2 in oxidation with KMnO4
terminal alkenes
45
formed in a cold alkaline medium
diol