C2 p1 slides Chemistry, Carbohydrates Flashcards

1
Q

Electrons are organized into shells that hold ?, ?, ? and ? electrons

A

2,8,8,18

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2
Q

Covalent bond strength

A

90 kcal/mol

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3
Q

Ionic bond strength in Vacuum

A

80 kcal/mol

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4
Q

Ionic bond strength in water

A

3 kcal/mol

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5
Q

H-bond strength in vacuum

A

4 kcal/mol

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6
Q

H-bond strength in water

A

1 kcal/mol

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7
Q

van der waals forces

A

contact distance between any two non-covalently bound atoms is the sum of their van der waals radii

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8
Q

blood ph

A

7.2

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9
Q

Buffer solutions contain a ? and its ?

A

weak acid, conjugate base

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10
Q

esters are formed by combining ? and ?

A

acid and alcohol

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11
Q

amides are formed by combining ? and ?

A

amine and acid

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12
Q

a nitrogen adjacent to a carbonyl carbon

A

amide

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13
Q

vitamins provide essential ?

A

cofactors

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14
Q

Carbohydrate general formula

A

Cn(H2O)n

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15
Q

glycogen is stored in ? and ?

A

muscle, liver

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16
Q

chitin and cellulose are polymers of ?

A

glucose

17
Q

glucose storage in mammals

A

glycogen

18
Q

glucose storage in plants

A

starch

19
Q

blood type is determined by expression of certain ?

A

glycolipids

20
Q

In a carbohydrate, if the -OH group on the last chiral carbon from the carbonyl carbon is pointing left, which enenatiomer is shown?

A

L

21
Q

In ring conformation, the -OH on the carbon adjacent to two oxygens is pointing up, which anomer is shown?

A

beta

22
Q

three carbohydrate uses

A

energy storage, structure, signalling

23
Q

sugars that differ in configuration at only one carbon

A

epimers

24
Q

monosaccharide units are joined by ?

A

glycosidic linkage

25
Q

carbohydrate enantiomers found in humans

A

L

26
Q

Use of branching in glycogen

A

creates multiple starting points for access to glucose

27
Q

? Glycosidic linkage wants to keep flat

A

beta

28
Q

Starch is a polymer of ?-glucose

A

alpha

29
Q

Cellulose is a polymer of ?-glucose

A

beta

30
Q

glycogen is a polymer of glucose with ? And ? Linkages

A

alpha(1,4) and alpha(1,6)

31
Q

glucose hydroxyl group of sugar replaced with carboxyl

A

glucuronic acid

32
Q

glucose hydroxyl group of sugar replaced with amine

A

glucosamine

33
Q

one kcal = ? kj

A

4.2

34
Q

kcal

A

amount of energy required to raise temperature of water by 1 degree Celsius

35
Q

Macro molecules make up this percent of cells

A

26%