bcm32 Flashcards
trigylcerol storage
adipocytes
lipid lipid intereaction
vdw
dipoles
head = phillic + tail = phobic=?
amphipathic
3 main lipid groups
glycerophospholipids
terpenes
sphingolipids
where are pgls made
surface of ser
how pgls distributed
assymetrically
fippases
recognise lipids with amine head and move to cytosolic leaflet use atp
scramblase
transverse flipflop no atp
properties of phosphatidyl choline
main pgl in eukaryotes
=lecithins
properties of phosphatidyl glycerol
cross linked to other lipids via head
properties of phosphatidyl serine
negative charge contributes to membrane potential
- presence in ex leaflet = apoptosis
properties of phosphatifyl ethanol amine
main pgl in bacteria
properties of phosphatidyl inositol
cell signaling pathway.
olive oil
oleic acid
cocoa butter
unusual very saturated
stearic acid
pokilotherms
cold water fish plants
unsaturated fats
homeotherms
birds mammals
saturated fats
sphingolipid structuralescription
sphingosine backbone replaces glycerol and 1 fatty acid
sphingolipid analogue of phosphatidyl choline
sphingomyeline
sphingolipid function description
nerve and brain cell membranes
glycolipids role, properties, example
ns
compact and impermeable, may form lipid raft
galactocerebroside, myelin
terpenes examples
terpenoid isoprenoid prenyllipid sterols and steroids isoprene retinal vitamin squalene cholesterol
lauric acid
12 carbon mp 43
myristic acid
14 carbon 54mp
palmitic acid
16 carbon 63mp
stearic acid
18 carbon 70mp
steric acid type mp
saturated 70mp
oleic acid
monounsaturated 13mp
linolenic acid
polyunsaturated -10
prenyl groups
covalently link to terpenes to anchor them to membrane
cholesterol effect on fluidity
conflicting
ring steroids stiffen-less fluid but also interfere with crystallisation of fatty acid chains and prevent freezing
rab protein
protein family of gtpases that regulate many steps of membrane traffic and vesciles
methanopyrus
archea live in black smokers
methyl groups reduce rotation
thermoplasma
no cell wall lipids span membrane lives at ph2 60 degrees gel like monolayer not fluid mosaic
hymothermophiles membrane
gel like transmembrane lipid
archea membrane lipid
terpene alcohol side chain
often lack head group
have ether bonds
allows to resit hydrolysis in extreme conditions