6.2.2: Reactions of Aromatics Flashcards
1
Q
Equation for formation of a nitronium ion
A
HNO3 + H2SO4 > HSO4- + NO2+ + H2O
2
Q
Nitronium ion
A
NO2+
3
Q
Electrophile in nitration
A
NO2+
4
Q
Mononitration
A
only one NO2 group added
5
Q
How to achieve mononitration in nitration
A
keep temp. below 55 degrees C
6
Q
Uses of nitration reactions
A
to manufacture:
dyes and pharmaceuticals
used as explosives:
TNT
7
Q
Catalyst in friedel-crafts acylation
A
AlCl3
8
Q
Overall word equation and conditions for friedel-crafts acylation
A
Acyl chloride + Benzene > Phenylketone + HCl
catalyst: AlCl3
Conditions: heated under reflux in a non-aqueous solvent eg: dry ether