6.2.1: Aromatic compounds Flashcards
Aromatic compounds
Contain a benzene ring
Benzene molecular formula
C6H6
Benzene structure
planar cyclic structure
Benzene bonding
Each carbon forms two single covalent bonds to the carbon atoms on either side of it and one to the hydrogen atom. Final unpaired electron located in the p-orbital which sticks out above and below the plane of the ring
P-orbitals on each carbon in benzene
p-orbitals can combine to form a new ring of delocalised electrons and all the bonds in the ring are the same length which is between a single or double bond.
How is the delocalised ring of electrons in benzene drawn
as a circle
What indicates a more stable compound
more energy required when breaking bonds so its more stable
Why is benzene more stable than cyclohexa-1,3,5-triene
In a delocalised ring the electron density is shared over more atoms which means the energy of the molecule is lowered and its becomes more stable
Naming aromatics
if the benzene ring is the main FG
if the benzene ring isn’t the main FG
main FG: suffix; -benzene
not main FG: preffix; -phenyl/phen